{"id":"W2049517432","doi":"10.1016/j.chroma.2011.05.079","title":"Effect of cyclization of N-terminal glutamine and carbamidomethyl-cysteine (residues) on the chromatographic behavior of peptides in reversed-phase chromatography","year":2011,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Manitoba; Research Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chromatography; Glutamine; Cysteine; Reversed-phase chromatography; High-performance liquid chromatography; Amino acid; Biochemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006847121,0.0006525683,0.0003006109,0.0002324511,0.0002882479,0.0003811186,0.0003681961,0.0005017137,0.002447907],"category_scores_gemma":[0.001289926,0.0002736627,0.0003194118,0.0003053376,0.0006622444,0.0004330643,0.0001741603,0.0006462932,0.0005770837],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000434115,"about_ca_system_score_gemma":0.0009830522,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001361055,"about_ca_topic_score_gemma":0.001981983,"domain_scores_codex":[0.9995711,0.0001501753,0.00003109624,0.00006341298,0.00005311264,0.0001310023],"domain_scores_gemma":[0.9988067,0.0005736467,0.0001615594,0.00006688003,0.0001193042,0.0002718377],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003897462,0.0001356428,0.0002497075,0.00006404208,0.00003281035,0.0001571377,0.00007637638,0.0001801725,0.99306,0.00006409291,0.00007004795,0.002012513],"study_design_scores_gemma":[0.00005195279,0.0008688065,0.001038538,0.000005065978,0.00002014401,0.00008231372,0.00002102914,0.0002370767,0.9972252,0.00001265611,0.0004265947,0.0000107114],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969509,0.0007836705,0.0009019717,0.0000970152,0.00005543185,0.00003200992,0.0001101679,0.00005192613,0.001016924],"genre_scores_gemma":[0.9959965,0.0007217372,0.001584034,0.0001178896,0.00004755429,0.00002166911,0.0004502944,0.00005463431,0.001005636],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002447907,"threshold_uncertainty_score":0.008189023,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01250081038405378,"score_gpt":0.2577227099379404,"score_spread":0.2452218995538867,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}