{"id":"W2049597096","doi":"10.1021/jp808208v","title":"High Temperature End of the So-Called “Koga Line”: Anomalies in Temperature Derivatives of Heat Capacities","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Isobaric process; Extrapolation; Thermodynamics; Chemistry; Heat capacity; Mole fraction; Calorimetry; Aqueous solution; Differential scanning calorimetry; Dilution; Boiling point; Work (physics); Organic chemistry; Physical chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001770788,0.0002303603,0.0005263847,0.00002267538,0.00005247701,0.00001331659,0.0007534876,0.0001227618,0.00003305523],"category_scores_gemma":[0.0002441747,0.0001174614,0.0002370727,0.0001853942,0.000457377,0.0001066222,0.0000761181,0.0009462092,2.874239e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006382457,"about_ca_system_score_gemma":0.00007492197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000017065,"about_ca_topic_score_gemma":0.000001779123,"domain_scores_codex":[0.9987521,0.00006623665,0.0004809582,0.0001021258,0.000390087,0.0002085219],"domain_scores_gemma":[0.998979,0.0002223933,0.0002520351,0.000339934,0.0001555786,0.00005103857],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002452117,0.0001542098,0.00001087123,0.000113797,0.00007095543,0.000003167036,0.002185724,0.0130026,0.9838855,0.000176298,0.0000670416,0.00008461548],"study_design_scores_gemma":[0.0005906462,0.00008738694,0.0005515451,0.0003838198,0.0000436907,0.00003236133,0.0007822048,0.0008160119,0.9956537,0.0009153417,0.00001702647,0.0001262593],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977818,0.0007173263,0.000005448173,0.001112665,0.00003917295,0.00006712662,0.00002281876,0.00001075785,0.0002429214],"genre_scores_gemma":[0.9992429,0.00003026411,0.00006573493,0.00006875174,0.0003751527,0.000001035565,0.000002034118,0.00001735822,0.0001967375],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01218659,"threshold_uncertainty_score":0.4789937,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004543750503331596,"score_gpt":0.1971156949422445,"score_spread":0.192571944438913,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}