{"id":"W2049612091","doi":"10.1021/ic010145m","title":"Interaction of Ferrocenoyl-Dipeptides with 3-Aminopyrazole Derivatives:  β-Sheet Models? A Synthetic, Spectroscopic, Structural, and Electrochemical Study","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; U.S. Consumer Product Safety Commission","keywords":"Chemistry; Dipeptide; Stereochemistry; Hydrogen bond; Peptide; Acetonitrile; Supramolecular chemistry; Electrochemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001048873,0.0002121342,0.0001502146,0.00006108075,0.0000708459,0.0001661964,0.0002066682,0.0002883267,0.0003493014],"category_scores_gemma":[0.0001464728,0.00009913269,0.000108192,0.00009065065,0.0001079879,0.0001546569,0.0000621088,0.0003257751,0.0001147187],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000156619,"about_ca_system_score_gemma":0.0000398919,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003409926,"about_ca_topic_score_gemma":0.0003911988,"domain_scores_codex":[0.9999208,0.000015284,0.000003722866,0.00001456797,0.00002924853,0.00001636133],"domain_scores_gemma":[0.9999225,0.00002709361,0.00002353828,0.000004930881,0.00001233089,0.000009700138],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003555407,0.00001642683,0.00006489581,0.00002122047,0.000003464421,0.00005249257,0.00001723659,0.0001176861,0.9989911,0.00002512925,0.00001155009,0.0006431297],"study_design_scores_gemma":[0.000004671326,0.0001539548,0.001114036,0.000002972262,0.000005311384,0.0001426965,0.00001618823,0.00129539,0.9967907,0.00001346042,0.0004571413,0.000003424179],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972245,0.0008458019,0.001218106,0.00003453283,0.000005512059,0.000009890548,0.00004009846,0.00001505427,0.0006066749],"genre_scores_gemma":[0.9979113,0.0004885819,0.00105977,0.00002363732,0.000003498542,0.000007855865,0.0000683718,0.000004090241,0.0004330051],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0003493014,"threshold_uncertainty_score":0.001168549,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01189231797083407,"score_gpt":0.2452352656575241,"score_spread":0.2333429476866901,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}