{"id":"W2049612091","doi":"10.1021/ic010145m","title":"Interaction of Ferrocenoyl-Dipeptides with 3-Aminopyrazole Derivatives:  β-Sheet Models? A Synthetic, Spectroscopic, Structural, and Electrochemical Study","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; U.S. Consumer Product Safety Commission","keywords":"Chemistry; Dipeptide; Stereochemistry; Hydrogen bond; Peptide; Acetonitrile; Supramolecular chemistry; Electrochemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004502269,0.0003676373,0.000383773,0.00002053708,0.0001401376,0.00004843785,0.0003331325,0.0001703109,0.001722231],"category_scores_gemma":[0.00005322586,0.0003410785,0.00005303051,0.0002341894,0.0002122183,0.0001979402,0.0001184434,0.0004328401,0.000005531311],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00013116,"about_ca_system_score_gemma":0.00008743353,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002112391,"about_ca_topic_score_gemma":0.000006715546,"domain_scores_codex":[0.9982991,0.000007117492,0.0004209331,0.000634729,0.0002723307,0.0003658254],"domain_scores_gemma":[0.9988128,0.00008968004,0.0002395982,0.0005746094,0.0001271401,0.0001561644],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001734895,0.0003021138,0.005303252,0.0002628766,0.0001019717,0.000008955929,0.0005795846,0.00001825633,0.9930551,0.00001633753,0.00003875683,0.0001393284],"study_design_scores_gemma":[0.0009178897,0.00004257241,0.0003208739,0.0001118532,0.00009333535,0.0002208776,0.004164953,0.0005645286,0.9927508,0.0003719901,0.00008637385,0.0003539874],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863663,0.0001519982,0.000177769,0.0000791971,0.000007519717,0.000118653,0.00001251329,0.0001086751,0.01297733],"genre_scores_gemma":[0.9985546,0.00007087506,0.0002627034,0.00001614132,0.0001148406,0.00005076491,0.00005245472,0.00004470128,0.0008329534],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01218822,"threshold_uncertainty_score":0.9999041,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01189231797083407,"score_gpt":0.2452352656575241,"score_spread":0.2333429476866901,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}