{"id":"W2050026500","doi":"10.1139/v03-142","title":"Organometallic reactions in aqueous media Bismuth-mediated crossed aldol type reactions","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Aldol reaction; Chemistry; Aqueous medium; Bismuth; Aqueous solution; Regioselectivity; Zinc; Fluoride; Organic chemistry; Inorganic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003334393,0.0001987974,0.0003594878,0.0002885679,0.0001334227,0.00007113563,0.0003146485,0.0002766213,0.007487078],"category_scores_gemma":[0.004152556,0.0002048226,0.0001719241,0.001142058,0.000126619,0.0001332007,0.000006557381,0.0006096441,0.0000574307],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000552471,"about_ca_system_score_gemma":0.002150754,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002332848,"about_ca_topic_score_gemma":0.003570979,"domain_scores_codex":[0.9984021,0.00002373958,0.0007062373,0.0002047365,0.0002434491,0.0004197106],"domain_scores_gemma":[0.9978075,0.0003144212,0.0004090609,0.0003560932,0.0002720972,0.000840811],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005804823,0.0003200631,0.02081921,0.0003070201,0.0007195531,0.001891236,0.001429557,0.0001235488,0.9444911,0.0001049433,0.010746,0.0189897],"study_design_scores_gemma":[0.0007742819,0.000009281922,0.0007353327,0.0001474862,0.000111334,0.0009622829,0.003059454,0.00001652679,0.6317149,0.0001775178,0.3618773,0.0004143478],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9052265,0.003040313,0.00001628022,0.0003282442,0.0002835309,0.00002832633,0.00005768813,0.00001864293,0.09100042],"genre_scores_gemma":[0.9967034,0.0001523973,0.00008831631,0.00005297184,0.0002000958,0.000003090045,0.00003641801,0.00003616434,0.002727186],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3511313,"threshold_uncertainty_score":0.9934202,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01381880190991218,"score_gpt":0.2101824515601095,"score_spread":0.1963636496501973,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}