{"id":"W2050649040","doi":"10.1126/science.1208710","title":"Direct Observation of Molecular Preorganization for Chirality Transfer on a Catalyst Surface","year":2011,"lang":"en","type":"article","venue":"Science","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":86,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Chirality (physics); Chemisorption; Substrate (aquarium); Catalysis; Scanning tunneling microscope; Active site; Chemical physics; Stereoselectivity; Density functional theory; Stereochemistry; Computational chemistry; Nanotechnology; Organic chemistry; Materials science; Chiral symmetry breaking; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000200696,0.00005426439,0.00006846363,0.00001768393,0.00003601604,0.000006867436,0.0001488754,0.00002257221,0.00001502149],"category_scores_gemma":[0.00005291884,0.00005335043,0.00002585785,0.0004869997,0.00006907563,0.0001393822,0.000005298765,0.00002076588,0.000002373023],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002356092,"about_ca_system_score_gemma":0.00001771981,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008116467,"about_ca_topic_score_gemma":0.000001588283,"domain_scores_codex":[0.9995472,0.000003168327,0.00009315171,0.0001287138,0.0001276205,0.0001001741],"domain_scores_gemma":[0.9997091,0.00001093645,0.000009850159,0.0001723862,0.00006922589,0.00002845125],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000003966799,0.0000130723,0.000890961,0.00003776798,0.000004610845,9.690583e-8,0.0004448727,0.006896506,0.991448,0.00009424135,0.000002966936,0.0001628881],"study_design_scores_gemma":[0.00005947724,0.00001278344,0.006664924,0.000007885368,0.000009972432,1.389795e-7,0.00002544026,0.001685026,0.991412,0.00004573207,0.00001609938,0.0000605254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9850527,0.00002759822,0.01260988,0.000005057027,0.000054956,0.00008361741,0.00001297231,0.00005475086,0.00209848],"genre_scores_gemma":[0.9991663,0.000002788376,0.0007627828,0.000006421373,0.000003491039,0.000003782043,0.00001140796,0.000006246701,0.0000368405],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01411355,"threshold_uncertainty_score":0.2175567,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0233052837375613,"score_gpt":0.2115499174765857,"score_spread":0.1882446337390244,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}