{"id":"W2050697886","doi":"10.1021/ol100511d","title":"Desymmetrizations Forming Tetrasubstituted Olefins Using Enantioselective Olefin Metathesis","year":2010,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Brock University","funders":"California Institute of Technology","keywords":"Chemistry; Olefin metathesis; Enantioselective synthesis; Carbene; Olefin fiber; Catalysis; Aryl; Alkyl; Group (periodic table); Metathesis; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002818322,0.0005595229,0.0003292503,0.000336548,0.0001621331,0.0002644727,0.0005160713,0.0003320368,0.001484935],"category_scores_gemma":[0.0002654683,0.0001865805,0.0003357172,0.000291264,0.0002417649,0.0003021965,0.0003156917,0.0004921622,0.0004712509],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004077043,"about_ca_system_score_gemma":0.0003256177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007763781,"about_ca_topic_score_gemma":0.001993102,"domain_scores_codex":[0.9997614,0.00002550664,0.00002147459,0.00003943759,0.00005541251,0.00009684087],"domain_scores_gemma":[0.9998895,0.00001659599,0.0000328516,0.0000234045,0.00001706721,0.00002052245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000154546,0.00007179712,0.0002158457,0.00006562751,0.00001948999,0.0002799497,0.00005245151,0.0006466173,0.9907334,0.0008716748,0.0002213668,0.006667193],"study_design_scores_gemma":[0.00002324897,0.0002454632,0.0003819714,0.000003185418,0.00001322731,0.0001575229,0.00001318555,0.0006646615,0.9963713,0.0000716002,0.002046136,0.000008484943],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9825584,0.0008171654,0.006821496,0.0001425097,0.00007653573,0.00008229633,0.0004923008,0.0002318964,0.008777353],"genre_scores_gemma":[0.9935837,0.0007075908,0.003157625,0.00003506499,0.00001078335,0.00002293353,0.00027497,0.00003460736,0.002172587],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001484935,"threshold_uncertainty_score":0.00496757,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.018163538617797,"score_gpt":0.2576538639555807,"score_spread":0.2394903253377836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}