{"id":"W2050852019","doi":"10.1021/jp020800r","title":"Anisotropic <sup>11</sup>B and <sup>13</sup>C NMR Interaction Tensors in Decamethylcyclopentadienyl Boron Complexes","year":2002,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Electric field gradient; Chemistry; Quadrupole; Coupling constant; Chemical shift; Boron; Nuclear magnetic resonance spectroscopy; Carbon-13 NMR satellite; Anisotropy; Carbon-13 NMR; Nuclear magnetic resonance; Crystallography; Resonance (particle physics); Physical chemistry; Fluorine-19 NMR; Stereochemistry; Atomic physics; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001170113,0.0002361429,0.000363067,0.00002616039,0.000129918,0.00003865822,0.0003947479,0.00009357742,0.0004202184],"category_scores_gemma":[0.00007788025,0.0001774069,0.0001370707,0.0001689401,0.0001870853,0.0002330553,0.0001045436,0.0006927956,0.000009127757],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000143494,"about_ca_system_score_gemma":0.00001240361,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003570328,"about_ca_topic_score_gemma":0.00000298095,"domain_scores_codex":[0.9987872,0.00003360888,0.0004452672,0.0002054808,0.0002487798,0.0002796121],"domain_scores_gemma":[0.9988165,0.0002953716,0.0003301172,0.0003363221,0.00008571615,0.0001359405],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001839472,0.001089422,0.0009290178,0.0002501267,0.00009267605,0.00003255508,0.003107204,0.1024723,0.8809794,0.0002900205,0.001790917,0.008782397],"study_design_scores_gemma":[0.002662807,0.000209575,0.0005687326,0.0006410375,0.0002783914,0.0008598675,0.006507856,0.3794582,0.5672641,0.006970914,0.03372188,0.0008566343],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995311,0.0001934272,0.000571189,0.0004909844,0.000001207893,0.00007177777,0.00001508718,0.00003779849,0.003307507],"genre_scores_gemma":[0.9983495,0.000265025,0.0003688183,0.00006586077,0.0004159083,0.00001229902,0.000005544457,0.00002767235,0.0004893902],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3137153,"threshold_uncertainty_score":0.7234445,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01696979203558982,"score_gpt":0.2771684969123568,"score_spread":0.260198704876767,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}