{"id":"W2051469896","doi":"10.1002/anie.201205741","title":"Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex","year":2012,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":153,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Ruthenium; Tris; Frustrated Lewis pair; Carbon dioxide; Chemistry; Orange (colour); Aldehyde; Lewis acids and bases; Organic chemistry; Catalysis; Food science; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000664176,0.0001968467,0.000279541,0.00008796314,0.0002492542,0.0005220474,0.0004902416,0.000500133,0.002318562],"category_scores_gemma":[0.0001261758,0.0001350662,0.0001156493,0.0001066738,0.0002906537,0.000258504,0.0003678109,0.000390254,0.0003483345],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003789839,"about_ca_system_score_gemma":0.0001834229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007123211,"about_ca_topic_score_gemma":0.0008394835,"domain_scores_codex":[0.9999214,0.000009367425,0.000002899779,0.00001833439,0.00002159497,0.00002642215],"domain_scores_gemma":[0.9999639,0.000008892483,0.000005470845,0.000005509895,0.000003072433,0.00001307848],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003009555,0.00009711114,0.000195925,0.00016189,0.00003480111,0.0006167382,0.0001192114,0.005559398,0.9778195,0.008671901,0.001639114,0.004783442],"study_design_scores_gemma":[0.0002509197,0.0007247658,0.0007958986,0.00001205735,0.00003506977,0.0006266514,0.0000863203,0.07120874,0.9130321,0.001602646,0.01156034,0.00006455351],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9827607,0.0002876047,0.005829681,0.0002689991,0.00006592658,0.00002187964,0.00007125073,0.0003280996,0.01036589],"genre_scores_gemma":[0.9960376,0.00006987864,0.001829841,0.00004792878,0.000004306627,0.00001059338,0.00004733531,0.00002818528,0.001924309],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002318562,"threshold_uncertainty_score":0.007756352,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02119371363034541,"score_gpt":0.2501357613263256,"score_spread":0.2289420476959802,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}