{"id":"W2051522458","doi":"10.1021/jp909540c","title":"Coupled Electron/Proton Transfer Studies of Benzoquinone-Modified Monolayers","year":2010,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Electron transfer; Monolayer; Proton-coupled electron transfer; Proton; Redox; Reaction rate constant; Benzoquinone; Electrochemistry; Electrolyte; Kinetics; Physical chemistry; Chemical physics; Inorganic chemistry; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003604699,0.0004321556,0.0004324235,0.0002297099,0.000212985,0.0002726494,0.000665557,0.0005173511,0.001732116],"category_scores_gemma":[0.0003704247,0.0002175579,0.0003819622,0.0003236647,0.0001931389,0.0004645539,0.0003110565,0.0008533152,0.0003564763],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002599358,"about_ca_system_score_gemma":0.00007540444,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004341909,"about_ca_topic_score_gemma":0.0003660945,"domain_scores_codex":[0.999767,0.00004009036,0.00001589986,0.0000519069,0.00008248693,0.00004269179],"domain_scores_gemma":[0.9998298,0.00007065925,0.00002635086,0.00001475627,0.00004391895,0.00001454598],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003774374,0.00002128629,0.00003350304,0.0000606188,0.00001084464,0.00002589455,0.00006716132,0.00007429481,0.9989542,0.00007004096,0.00001899541,0.0006254443],"study_design_scores_gemma":[0.000008368491,0.0001809694,0.0006103904,0.000002988468,0.00001226232,0.0000395242,0.00002555705,0.001263817,0.9974505,0.00003280836,0.0003667933,0.000006003246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950331,0.0007379571,0.00325041,0.00003955119,0.00002106652,0.00003414442,0.0001172118,0.00004937349,0.0007170126],"genre_scores_gemma":[0.9931452,0.000987527,0.003899347,0.00004400083,0.00001668601,0.00005750141,0.0002107426,0.0000197093,0.001619263],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001732116,"threshold_uncertainty_score":0.005794466,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0130497510202756,"score_gpt":0.2848392346328346,"score_spread":0.271789483612559,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}