{"id":"W2051586337","doi":"10.1016/s0141-3910(02)00013-7","title":"Stabilization mechanism of antimony mercaptides in poly(vinyl chloride): ab initio theory studies","year":2002,"lang":"en","type":"article","venue":"Polymer Degradation and Stability","topic":"Polymer Science and PVC","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"","keywords":"Antimony; Electrophile; Nucleophile; Ab initio; Vinyl chloride; Chemistry; Decomposition; Computational chemistry; Materials science; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00109791,0.0001700543,0.0003193305,0.000190098,0.0001356752,0.00004376257,0.0001769978,0.00006587258,0.0008121803],"category_scores_gemma":[0.0003039473,0.0001436786,0.00004462793,0.0005010163,0.0004237767,0.0006955729,0.00007710686,0.00007775971,0.00001731286],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004385775,"about_ca_system_score_gemma":0.00003276256,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002030408,"about_ca_topic_score_gemma":0.0001846616,"domain_scores_codex":[0.9981622,0.0002849572,0.0005298202,0.0004143493,0.0003268851,0.0002817983],"domain_scores_gemma":[0.9990014,0.0003109197,0.0001743345,0.0003326382,0.0000978794,0.00008275734],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001406285,0.0004391282,0.02137868,0.0001731366,0.00002110231,0.000002625003,0.01160924,0.000001360469,0.7850159,0.1601487,0.00003740803,0.02103207],"study_design_scores_gemma":[0.0003309691,0.0000736935,0.004731558,0.00002874595,0.00001602681,0.000002637725,0.002371085,0.0005578012,0.9803632,0.01132729,0.00001913526,0.0001778084],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892998,0.007602793,0.0009354706,0.000398246,0.0002748175,0.000198418,0.00004638136,0.00004947251,0.001194631],"genre_scores_gemma":[0.9986412,0.000813494,0.0001590367,0.0001295154,0.00002258662,0.00002118633,0.000006226851,0.000008331956,0.0001984195],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1953473,"threshold_uncertainty_score":0.8892804,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06793396082423318,"score_gpt":0.2788040795908275,"score_spread":0.2108701187665943,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}