{"id":"W2051828902","doi":"10.1021/jo991360b","title":"Preparation of 4-Substituted Benzyl Sulfoxylates and Related Chemistry","year":2000,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"McGill University","keywords":"Chemistry; Isomerization; Toluene; Kinetics; Thermal stability; Organic chemistry; Computational chemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005189803,0.0002214336,0.000366683,0.00001661726,0.00008284685,0.00002189859,0.0004787754,0.0002723568,0.0203957],"category_scores_gemma":[0.0002817697,0.0001716304,0.000118251,0.0001839419,0.0002325239,0.0001365103,0.00004536417,0.0004832686,0.000006402794],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009206405,"about_ca_system_score_gemma":0.0001538452,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006998913,"about_ca_topic_score_gemma":6.044481e-7,"domain_scores_codex":[0.9984581,0.000025367,0.0008149271,0.0001589601,0.0003432673,0.0001993294],"domain_scores_gemma":[0.998318,0.0002566438,0.0006653705,0.0004791493,0.000176094,0.0001048054],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002257699,0.00008738561,0.0002593181,0.0001853377,0.0001246418,0.00001175748,0.0003155199,0.00001646526,0.9970555,7.96401e-7,0.0002694241,0.001448112],"study_design_scores_gemma":[0.0005460995,0.00001451506,0.0001066831,0.000222141,0.0001793623,0.0009977858,0.0001995985,0.00005429682,0.9967048,0.0002876244,0.0005215465,0.0001655536],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9840798,0.001281837,0.00001199943,0.0001666629,0.00001520859,0.00003718167,0.000008735556,0.00006186989,0.01433675],"genre_scores_gemma":[0.9972968,0.0007116683,0.0001759402,0.000009486959,0.0001191798,0.00000141306,0.000007652934,0.00003439159,0.001643449],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02038929,"threshold_uncertainty_score":0.9804998,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005960601333807566,"score_gpt":0.2351514766605192,"score_spread":0.2291908753267116,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}