{"id":"W2051995155","doi":"10.1002/ejic.201100057","title":"Iridium Phosphane Complexes Containing Arylspiroboronate Esters for the Hydroboration of Alkenes","year":2011,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"","keywords":"Chemistry; Hydroboration; Iridium; Rhodium; Denticity; Medicinal chemistry; Cyclooctene; Chelation; Organic chemistry; Metal; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005968897,0.0003002314,0.0004179221,0.00002282651,0.000131573,0.00003770118,0.0009099091,0.00008241818,0.002289009],"category_scores_gemma":[0.0002784823,0.0002364713,0.0002562529,0.0001276075,0.000234596,0.0001490525,0.0001193599,0.0003895432,0.000008577818],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007811056,"about_ca_system_score_gemma":0.0001626964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000609185,"about_ca_topic_score_gemma":9.805757e-7,"domain_scores_codex":[0.9980693,0.00003386844,0.001038228,0.0002407972,0.0003063683,0.0003113891],"domain_scores_gemma":[0.9975807,0.0002043499,0.001216649,0.0004703746,0.0003594866,0.0001684314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002722701,0.0001141372,0.001158694,0.0003096251,0.0001857486,0.00003985781,0.0009430468,0.00001153734,0.9948162,0.00001215082,0.0007272766,0.001409412],"study_design_scores_gemma":[0.001633964,0.0001002746,0.000617391,0.0001630636,0.0001614878,0.000271233,0.001518564,0.00003434955,0.9937056,0.00002755767,0.001523144,0.0002434011],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9880739,0.001928683,0.0007905249,0.0002708844,0.0002353828,0.00007517029,0.00004278586,0.00004848478,0.008534192],"genre_scores_gemma":[0.9981361,0.0001571599,0.0006801175,0.0001042292,0.0005344886,0.000001593761,0.00001575449,0.00008607395,0.0002844836],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01006221,"threshold_uncertainty_score":0.998623,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0270189514966926,"score_gpt":0.22169986471452,"score_spread":0.1946809132178274,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}