{"id":"W2052149500","doi":"10.1021/ma991798d","title":"Controlled Association of Amphiphilic Polymers in Water:  Thermosensitive Nanoparticles Formed by Self-Assembly of Hydrophobically Modified Pullulans and Poly(<i>N</i>-isopropylacrylamides)","year":2000,"lang":"en","type":"article","venue":"Macromolecules","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":158,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Lower critical solution temperature; Dynamic light scattering; Dispersity; Pullulan; Polymer chemistry; Polymer; Copolymer; Poly(N-isopropylacrylamide); Nanoparticle; Hydrodynamic radius; Amphiphile; Chemical engineering; Static light scattering; Materials science; Upper critical solution temperature; Fluorescence correlation spectroscopy; Size-exclusion chromatography; Hydrophobe; Fluorescence spectroscopy; Fluorescence; Chemistry; Organic chemistry; Nanotechnology; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001208176,0.0003923014,0.0001931657,0.0001071716,0.00007909745,0.000190413,0.0001593822,0.0002599762,0.0004214748],"category_scores_gemma":[0.0001669585,0.0001956491,0.0001542695,0.00008150378,0.0001907242,0.00036902,0.0002395861,0.0003287485,0.0002358179],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002051987,"about_ca_system_score_gemma":0.0001255634,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002295671,"about_ca_topic_score_gemma":0.0003162083,"domain_scores_codex":[0.999926,0.000008919918,0.000005651787,0.00002636926,0.00001505145,0.00001805485],"domain_scores_gemma":[0.9998991,0.00001940647,0.00003948027,0.000007329477,0.00001336262,0.0000212584],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000146307,0.00000360181,0.00001801248,0.0000101306,0.000001102697,0.000007363615,0.000004490766,0.00002950239,0.9996002,0.00002310917,0.000004243394,0.0002836226],"study_design_scores_gemma":[0.000003312397,0.00003425922,0.0001671505,0.00000100198,0.000003503112,0.00001830208,0.00000227831,0.0004437718,0.9990215,0.000009335229,0.0002940569,0.00000149531],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926307,0.0007028123,0.005829216,0.00003515124,0.00001739096,0.00002651394,0.00005587537,0.00007639588,0.0006260254],"genre_scores_gemma":[0.9934992,0.000370473,0.004531061,0.00002973946,0.000009482686,0.00003605827,0.00007587557,0.00003017526,0.00141807],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004214748,"threshold_uncertainty_score":0.001488864,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003469415243577809,"score_gpt":0.1881726561165931,"score_spread":0.1847032408730153,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}