{"id":"W2052149500","doi":"10.1021/ma991798d","title":"Controlled Association of Amphiphilic Polymers in Water:  Thermosensitive Nanoparticles Formed by Self-Assembly of Hydrophobically Modified Pullulans and Poly(<i>N</i>-isopropylacrylamides)","year":2000,"lang":"en","type":"article","venue":"Macromolecules","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":158,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Lower critical solution temperature; Dynamic light scattering; Dispersity; Pullulan; Polymer chemistry; Polymer; Copolymer; Poly(N-isopropylacrylamide); Nanoparticle; Hydrodynamic radius; Amphiphile; Chemical engineering; Static light scattering; Materials science; Upper critical solution temperature; Fluorescence correlation spectroscopy; Size-exclusion chromatography; Hydrophobe; Fluorescence spectroscopy; Fluorescence; Chemistry; Organic chemistry; Nanotechnology; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003014618,0.0002234032,0.0006481415,0.0000522153,0.00005127788,0.00002953522,0.000134194,0.0001796224,0.0002551889],"category_scores_gemma":[0.0000353015,0.0001717853,0.0001167547,0.0001258125,0.00005897586,0.00007461705,0.0000290967,0.0001069386,0.000004523741],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001050006,"about_ca_system_score_gemma":0.00003401699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001231709,"about_ca_topic_score_gemma":0.0001191567,"domain_scores_codex":[0.9981843,0.0001087776,0.0006595053,0.0002923555,0.0003474692,0.0004075472],"domain_scores_gemma":[0.9992694,0.0001546605,0.0002362983,0.0001969004,0.00006311529,0.00007967312],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000757324,0.0002233723,0.003238238,0.00007140356,0.0001574087,0.00001306765,0.0009160682,0.00000956144,0.9900037,0.00005393019,0.000007038628,0.004548876],"study_design_scores_gemma":[0.004941483,0.00007856851,0.000917479,0.00006621877,0.00005972915,0.00000696693,0.0002965165,0.001225641,0.9919727,0.0001719448,0.00004950719,0.0002132636],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936147,0.000563436,0.000003392953,0.0001739618,0.00001947333,0.000233534,0.00006386204,0.00004426346,0.005283347],"genre_scores_gemma":[0.9990918,0.00009013816,0.00001828054,0.00003706418,0.00001442692,0.00003139155,0.00001820825,0.00002828741,0.0006703903],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005477083,"threshold_uncertainty_score":0.70052,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003469415243577809,"score_gpt":0.1881726561165931,"score_spread":0.1847032408730153,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}