{"id":"W2052173112","doi":"10.1002/macp.200500516","title":"Modeling of Atom Transfer Radical Polymerization with Bifunctional Initiators: Diffusion Effects and Case Studies","year":2006,"lang":"en","type":"article","venue":"Macromolecular Chemistry and Physics","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Dispersity; Polymerization; Chemistry; Atom-transfer radical-polymerization; Diffusion; Polymer; Polymer chemistry; Radical polymerization; Monomer; Kinetic chain length; Molar mass distribution; Chain transfer; Thermodynamics; Yield (engineering); Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00001861037,0.0001656807,0.0001947346,0.000004856133,0.0001098126,0.00001538803,0.00002678522,0.00007396883,0.00001428587],"category_scores_gemma":[0.000004537917,0.0001478239,0.00003284291,0.00006710591,0.0001233722,0.00007580241,0.00002153824,0.00008052959,9.919158e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009019336,"about_ca_system_score_gemma":0.00001355904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000119089,"about_ca_topic_score_gemma":4.229207e-7,"domain_scores_codex":[0.9993562,0.00001019954,0.0001641368,0.0002243763,0.0001282378,0.000116917],"domain_scores_gemma":[0.9997324,0.0000366605,0.00004141369,0.0001069502,0.00003871681,0.00004386984],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005125821,0.000093123,0.0006443788,0.0008024753,0.00005907112,0.0001518646,0.0001304685,0.0001922467,0.9951511,0.0002736441,4.007225e-7,0.00244994],"study_design_scores_gemma":[0.0005654953,0.00001439471,0.00001843788,0.0001493158,0.0000955203,0.0004117389,0.00009329087,0.01091521,0.9872181,0.0003189681,0.00001916276,0.0001803426],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9106864,0.0009096123,0.08812428,0.000009922964,0.000009445708,0.00003133392,0.00002551634,0.00002179755,0.0001817286],"genre_scores_gemma":[0.9993358,0.00008450176,0.0002630733,0.00001514406,0.0001253345,0.00001170101,0.0001158567,0.00002111389,0.00002750158],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0886494,"threshold_uncertainty_score":0.6028084,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005585061700881941,"score_gpt":0.2063294883531182,"score_spread":0.2007444266522362,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}