{"id":"W2052330571","doi":"10.1034/j.1399-3011.2002.201000.x","title":"Synthesis of cyclopentapeptides and cycloheptapeptides by DEPBT and the influence of some factors on cyclization","year":2002,"lang":"en","type":"article","venue":"Journal of Peptide Research","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Hospital for Sick Children","funders":"","keywords":"Reagent; Cyclic peptide; Chemistry; Peptide; Yield (engineering); Combinatorial chemistry; Coupling (piping); Coupling reaction; Stereochemistry; Organic chemistry; Biochemistry; Materials science; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001035373,0.0001084076,0.000321425,0.000118934,0.00008069006,0.00002744932,0.0002327582,0.00008690501,0.000031297],"category_scores_gemma":[0.001817493,0.0000657498,0.000133782,0.000157146,0.0005770911,0.00001804086,0.0001061486,0.0001775103,6.984628e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001243139,"about_ca_system_score_gemma":0.00001618229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006073763,"about_ca_topic_score_gemma":0.000007560223,"domain_scores_codex":[0.9984993,0.000247237,0.0004555144,0.0001559662,0.0004663219,0.0001756383],"domain_scores_gemma":[0.9984974,0.0006563711,0.0002995102,0.0001839699,0.0002669227,0.00009579606],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001780571,0.0001068502,0.02214769,0.00005142154,0.0001666002,0.000001201983,0.0001022376,0.00008593007,0.9723372,0.00009621439,0.001235594,0.00349097],"study_design_scores_gemma":[0.0006084504,0.0002884331,0.02283997,0.0001857803,0.00006889604,0.00001228772,0.0004381316,0.00008378356,0.9738423,0.000309334,0.001214872,0.0001077667],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970645,0.002190389,0.000007877016,0.0003381607,0.000005671594,0.00007276599,0.00001122176,8.496307e-7,0.0003085869],"genre_scores_gemma":[0.9890547,0.01064301,0.00007418348,0.00002550032,0.00005292284,0.000002799395,0.000001392899,0.0000107231,0.0001347357],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008452626,"threshold_uncertainty_score":0.2681199,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02037344601873442,"score_gpt":0.2899386153012627,"score_spread":0.2695651692825283,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}