{"id":"W2052523180","doi":"10.1021/om050847+","title":"<i>s</i>-<i>trans</i>-Diene Complexes of a First-Row Transition Metal. Half-Sandwich <i>s</i>-<i>trans</i>-η<sup>4</sup>-1,3-Diene Nitrosyl Complexes of Chromium","year":2006,"lang":"he","type":"article","venue":"Organometallics","topic":"Conducting polymers and applications","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Diene; Decarbonylation; Chromium; Transition metal; Alkyne; Olefin fiber; Conjugated diene; Metal; Conjugated system; Medicinal chemistry; Crystallography; Stereochemistry; Polymer chemistry; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001293107,0.001370063,0.002760956,0.0006339019,0.0009092361,0.0002505134,0.001709345,0.0005846724,0.005077905],"category_scores_gemma":[0.00007932715,0.001415901,0.001095152,0.00272349,0.002118767,0.0007627079,0.0002166878,0.000582866,0.0000697868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001686473,"about_ca_system_score_gemma":0.0003571276,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004662812,"about_ca_topic_score_gemma":0.001243468,"domain_scores_codex":[0.9913757,0.0004263879,0.003257375,0.001775077,0.001504658,0.00166073],"domain_scores_gemma":[0.9946967,0.000605906,0.001496346,0.001928675,0.0008337998,0.0004386089],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002191895,0.002229285,0.0003621269,0.001544005,0.0003124212,0.00001153401,0.002754978,0.003070919,0.9864545,0.001494581,0.001304548,0.0002419086],"study_design_scores_gemma":[0.003117149,0.0005155479,0.0008136342,0.0003808035,0.001535564,0.00007632215,0.0008790835,0.0009168072,0.9431731,0.001310852,0.04592283,0.001358355],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9753572,0.006235386,0.006861477,0.00299752,0.000546167,0.001668649,0.004359578,0.0002599661,0.001714055],"genre_scores_gemma":[0.9915813,0.0008679327,0.004548084,0.0002488725,0.0006020618,0.0001196942,0.0008608303,0.0002485487,0.0009226599],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04461829,"threshold_uncertainty_score":0.999905,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01834687457940984,"score_gpt":0.2346395390672043,"score_spread":0.2162926644877944,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}