{"id":"W2052651535","doi":"10.1021/ac0494331","title":"Kinetics of Ion-Exchange Binding of Redox Metal Cations to Thiolate−DNA Monolayers on Gold","year":2004,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Redox; Kinetics; Metal; Monolayer; Inorganic chemistry; Ion exchange; Ion; Photochemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008056505,0.0004915203,0.0007058134,0.0002500275,0.0002262328,0.0005630911,0.0007155798,0.000547574,0.001853686],"category_scores_gemma":[0.001265895,0.0003650664,0.0002552937,0.0002357579,0.0003663703,0.0006802499,0.0002645797,0.0007238159,0.0008546085],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005843987,"about_ca_system_score_gemma":0.0001994638,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001105879,"about_ca_topic_score_gemma":0.001186525,"domain_scores_codex":[0.9994855,0.00007470907,0.00003195656,0.0001073857,0.0001954618,0.0001050004],"domain_scores_gemma":[0.9992542,0.0003941194,0.00008929373,0.00005342218,0.0001257897,0.00008319377],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000138166,0.000039533,0.0002293084,0.00008699481,0.00001644125,0.00003889524,0.0001078775,0.0003355028,0.9960138,0.0001762718,0.00007116314,0.002746093],"study_design_scores_gemma":[0.00001119258,0.0001222703,0.001057054,0.000004146016,0.000006888147,0.00003958958,0.00002363209,0.004638111,0.9932455,0.00005821113,0.0007800408,0.00001326955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9897266,0.001157977,0.006849227,0.0001164018,0.00003830012,0.0000657721,0.0002113263,0.0002307972,0.001603516],"genre_scores_gemma":[0.9863019,0.0009566755,0.006477403,0.00007755655,0.00001653384,0.00006504989,0.0003600345,0.00004257675,0.005702205],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001853686,"threshold_uncertainty_score":0.006201148,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01280332091564958,"score_gpt":0.2818341329432172,"score_spread":0.2690308120275677,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}