{"id":"W2053067260","doi":"10.1016/s0040-4039(02)02183-4","title":"On the regiochemistry of nucleophilic attack on 2-halo π-allyl complexes. Part 3: The electronic effect of phenoxide ion and the ligand","year":2002,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Denticity; Malonate; Nucleophile; Regioselectivity; Medicinal chemistry; Ligand (biochemistry); Dimethyl malonate; Propene; Stereochemistry; Palladium; Organic chemistry; Crystal structure; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007257281,0.0004054511,0.0002633822,0.0003240776,0.0002380169,0.0003914023,0.0009705949,0.0003627745,0.007796532],"category_scores_gemma":[0.0005826748,0.0002124291,0.0002167671,0.0001625188,0.0004509713,0.0005478079,0.0003445926,0.0003150141,0.001098434],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003546351,"about_ca_system_score_gemma":0.0001409879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003347831,"about_ca_topic_score_gemma":0.000585859,"domain_scores_codex":[0.9997362,0.00008128502,0.00001363601,0.0000308577,0.00005037403,0.00008754925],"domain_scores_gemma":[0.9997374,0.0001570508,0.0000429625,0.00003445165,0.00001598573,0.00001219097],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.004311609,0.0001054608,0.0006831084,0.0004685908,0.0000505174,0.0006116314,0.0002974664,0.003071743,0.9539915,0.006716676,0.001522296,0.02816941],"study_design_scores_gemma":[0.0001063317,0.0009863134,0.001990495,0.00002144861,0.00003476562,0.0003166547,0.00007313146,0.003152716,0.9879205,0.001366451,0.004005552,0.00002570308],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9703118,0.005322785,0.003855998,0.0002726777,0.00009675191,0.00004094406,0.0002428991,0.0001846757,0.01967158],"genre_scores_gemma":[0.9943639,0.001850031,0.000472864,0.00005764174,0.00002996878,0.00001644376,0.0001123982,0.00003660244,0.00306012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007796532,"threshold_uncertainty_score":0.02608198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01395675335564254,"score_gpt":0.2059024808914904,"score_spread":0.1919457275358479,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}