{"id":"W2053134459","doi":"10.1002/1521-3773(20010601)40:11<2129::aid-anie2129>3.0.co;2-2","title":"Titanocene-Catalyzed Coupling of Amides in the Presence of Organosilanes To Form Vicinal Diamines","year":2001,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Vicinal; Deoxygenation; Catalysis; Coupling (piping); Chemistry; Coupling reaction; Polymer chemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000162973,0.00008973165,0.0001324599,0.0001606703,0.00002322223,0.00001368061,0.0003302383,0.00005534033,0.0005505875],"category_scores_gemma":[0.000333062,0.00007270362,0.00006247106,0.0004316206,0.00004206221,0.000150933,0.00003947337,0.00006795604,0.000006495821],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005740529,"about_ca_system_score_gemma":0.00002229019,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001049028,"about_ca_topic_score_gemma":0.00005777126,"domain_scores_codex":[0.9989861,0.000002633903,0.0003155351,0.0001476579,0.0004468622,0.0001012578],"domain_scores_gemma":[0.9992772,0.0001895473,0.0001616494,0.0001530286,0.0001903096,0.00002823799],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008799502,0.0001832423,0.02270078,0.00006368194,0.00006179746,0.00001117458,0.0008463295,0.0002116054,0.9731905,0.0002823517,0.001313105,0.001047391],"study_design_scores_gemma":[0.000298884,0.000008511988,0.002054653,0.00006752431,0.00001772203,0.00001489218,0.0006297455,0.0003616647,0.9950987,0.0001748213,0.001197642,0.00007521843],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899466,0.00007552061,0.0007147853,0.0005099078,0.0001193805,0.0000541751,0.00006492771,0.00001419071,0.008500515],"genre_scores_gemma":[0.9988561,0.0000969723,0.00006524538,0.00006051453,0.0002969165,0.00002585401,0.0003481016,0.000007438382,0.0002429146],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02190817,"threshold_uncertainty_score":0.6028547,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01536038849255679,"score_gpt":0.2629216096905862,"score_spread":0.2475612211980294,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}