{"id":"W2053320724","doi":"10.1139/v07-095","title":"Ketonization of the unusually acidic elongated enol generated by flash photolytic decarboxylation of <i>p</i>-formylphenylacetic acid in aqueous solution","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Advanced Chemical Sensor Technologies","field":"Engineering","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Enol; Perchloric acid; Aqueous solution; Acetic acid; Decarboxylation; Solvent; Flash photolysis; Photodissociation; Photochemistry; Kinetic isotope effect; Inorganic chemistry; Organic chemistry; Reaction rate constant; Deuterium; Catalysis; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004465869,0.000122118,0.0002160386,0.00007737691,0.0000327939,0.000004392058,0.0002530637,0.0001728131,0.0000190689],"category_scores_gemma":[0.0002378815,0.0001124615,0.00005566904,0.0004804689,0.0002061742,0.00008857426,0.000008426891,0.0002919746,4.113979e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003977496,"about_ca_system_score_gemma":0.0001807767,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001384681,"about_ca_topic_score_gemma":0.0003383444,"domain_scores_codex":[0.999065,0.000009857703,0.0004847332,0.00007574235,0.000152965,0.0002116333],"domain_scores_gemma":[0.9993203,0.00001969748,0.0002266494,0.000163687,0.0001634845,0.0001062098],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000005856854,0.000006094394,0.001029924,0.00005344614,0.00001631418,0.00001129274,0.0001087719,0.0144062,0.983374,8.183566e-7,0.0002899681,0.0006972934],"study_design_scores_gemma":[0.000335696,0.00001167306,0.0003341869,0.00009947987,0.00001070053,0.0001036387,0.00004805233,0.004049607,0.994733,0.00007498659,0.0000998166,0.00009910778],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975759,0.001402913,0.0004899087,0.0000544934,0.00005912939,0.00006432307,0.00001752745,0.00002262482,0.0003132175],"genre_scores_gemma":[0.9995741,0.000126413,0.0002089438,0.000007749913,0.00001695279,0.000001436383,0.00001043188,0.00002019638,0.00003377171],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01135904,"threshold_uncertainty_score":0.4586048,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005360124739330935,"score_gpt":0.163496570178067,"score_spread":0.1581364454387361,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}