{"id":"W2053346816","doi":"10.1021/ja011110o","title":"Divergent Selectivity in MgI<sub>2</sub>-Mediated Ring Expansions of Methylenecyclopropyl Amides and Imides","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":124,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"University of Toronto","keywords":"Chemistry; Selectivity; Ring (chemistry); Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002235079,0.0001832008,0.0004940754,0.00003385229,0.00007397812,0.00001455711,0.0002769261,0.00008723232,0.00004252903],"category_scores_gemma":[0.0004029723,0.0001337233,0.00039719,0.00043552,0.0003240847,0.0001131447,0.0001867992,0.0006803813,0.000001333775],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003221653,"about_ca_system_score_gemma":0.00003805731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007585138,"about_ca_topic_score_gemma":0.000005270439,"domain_scores_codex":[0.9985313,0.00004949153,0.0005188556,0.0001946971,0.0004399504,0.0002656618],"domain_scores_gemma":[0.9983131,0.0003062101,0.0008856229,0.0002138524,0.0001482047,0.0001330641],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002712403,0.0001466759,0.00570054,0.00005780775,0.00009206721,0.000002899048,0.0007339386,0.00003112235,0.9826366,0.000002638758,0.0001429543,0.01042562],"study_design_scores_gemma":[0.0004723992,0.00002879158,0.002880151,0.00008853818,0.00006394221,0.00006270759,0.001518259,0.0006091535,0.9939139,0.0001261597,0.0000926303,0.0001434015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989885,0.0003987563,0.00004759923,0.0003351971,0.00005290439,0.00004754907,0.000007817304,0.00001732399,0.0001043709],"genre_scores_gemma":[0.9972955,0.001436474,0.001048874,0.00008598904,0.00009759887,0.000003571369,6.681254e-7,0.00002235531,0.000008958952],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01127725,"threshold_uncertainty_score":0.5453076,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01243683794644484,"score_gpt":0.2264938196896758,"score_spread":0.214056981743231,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}