{"id":"W2053379067","doi":"10.1139/v05-088","title":"Anion effects in the formation of the active catalyst in the Ruhrchemie Rhône-Poulenc aqueous biphasic hydroformylation process. Are there any?","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Hungarian Scientific Research Fund; National Research Foundation","keywords":"Hydroformylation; Rhodium; Chemistry; Aqueous solution; Triphenylphosphine; Catalysis; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005150028,0.0003575147,0.0003042546,0.0001236473,0.0001319454,0.000562523,0.0003540681,0.0005667712,0.001908142],"category_scores_gemma":[0.0006653693,0.0002537712,0.0002053438,0.00009352135,0.0003282574,0.0008067375,0.0003311567,0.0005559943,0.0006087701],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003024554,"about_ca_system_score_gemma":0.0002141831,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006616997,"about_ca_topic_score_gemma":0.0008185741,"domain_scores_codex":[0.9996365,0.00009675142,0.00003138017,0.00007692333,0.00009753183,0.00006096881],"domain_scores_gemma":[0.9997358,0.00009818155,0.00008276283,0.00002150244,0.00003896538,0.00002280164],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006224227,0.00002173454,0.0002319724,0.0002204352,0.0000143885,0.0001822385,0.0000735827,0.0001523949,0.9949609,0.0003574142,0.00009491021,0.003067579],"study_design_scores_gemma":[0.0000309733,0.0002004148,0.0008023935,0.00001024225,0.0000171604,0.0001710269,0.00004765479,0.0006025101,0.9955669,0.0001066867,0.002434923,0.000009039042],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9849859,0.004892425,0.003602993,0.0005037661,0.0001196445,0.00007234397,0.0002221275,0.0001456539,0.005455059],"genre_scores_gemma":[0.9947035,0.001339474,0.00107699,0.000102373,0.00002240093,0.0000166647,0.00009960816,0.00001749244,0.002621393],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001908142,"threshold_uncertainty_score":0.006383419,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006681823145814635,"score_gpt":0.2136457088509328,"score_spread":0.2069638857051181,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}