{"id":"W2053515094","doi":"10.1021/ic100165t","title":"Coordinatively Diverse <i>ortho</i>-Phosphinoaniline Complexes of Ruthenium and Isolation of a Putative Intermediate in Ketone Transfer Hydrogenation Catalysis","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Medicinal chemistry; Diphosphines; Dichloromethane; Ruthenium; Transfer hydrogenation; Catalysis; Ketone; p-Cymene; Deprotonation; Amine gas treating; Solvent; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002125966,0.0002058598,0.0004126074,0.0001300563,0.0000377471,0.00001046474,0.0002111422,0.0002029667,0.000786895],"category_scores_gemma":[0.0002391533,0.0002168837,0.0001114616,0.0007101606,0.0002571791,0.0001475445,0.00007878347,0.0003147001,0.000002744133],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004844593,"about_ca_system_score_gemma":0.00007120644,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001697774,"about_ca_topic_score_gemma":0.00008358572,"domain_scores_codex":[0.9985538,0.00001418569,0.0006170853,0.0003355339,0.0003075342,0.0001719104],"domain_scores_gemma":[0.99904,0.0001467656,0.0002559826,0.0002561409,0.000213143,0.00008796346],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000486201,0.0002005051,0.01718233,0.000207412,0.0001028291,0.000002998318,0.001949107,0.00001061729,0.978543,0.0000504844,0.000003616477,0.001698496],"study_design_scores_gemma":[0.001152221,0.00001089928,0.002692147,0.00002315318,0.00010334,0.00000943991,0.001256943,0.001858492,0.9925703,0.00008539596,0.00005035028,0.0001873414],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997301,0.0001031648,0.0004035453,0.00005537061,0.0000201038,0.00006607442,0.0002111371,0.00002819085,0.001811365],"genre_scores_gemma":[0.9991748,0.0000380182,0.0001160767,0.00001064631,0.00002833507,0.000009661245,0.0004192266,0.00002151193,0.0001816721],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01449018,"threshold_uncertainty_score":0.8844261,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006177555750591862,"score_gpt":0.2215099579705267,"score_spread":0.2153324022199349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}