{"id":"W2053546764","doi":"10.1021/ol0257530","title":"Electrochemical Imination of Sulfoxides Using <i>N</i>-Aminophthalimide","year":2002,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Sulfoxide; Electrochemistry; Nitrene; Combinatorial chemistry; Cleavage (geology); Organic chemistry; Catalysis; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002772443,0.0006006446,0.0003405767,0.0001611504,0.0001616833,0.000235757,0.0006569812,0.0003138049,0.0008355233],"category_scores_gemma":[0.0002846354,0.0002625468,0.0001618878,0.0001491739,0.0002648217,0.0004562802,0.0002833493,0.0005680554,0.0003893996],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003425993,"about_ca_system_score_gemma":0.0001949029,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003281072,"about_ca_topic_score_gemma":0.0008195865,"domain_scores_codex":[0.9998116,0.00002496143,0.00001855139,0.00004548532,0.00007193827,0.00002737621],"domain_scores_gemma":[0.9998895,0.00003037978,0.00002951206,0.00001302147,0.00002228802,0.00001526257],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002828098,0.00001568041,0.00004307082,0.00009927249,0.000004849221,0.00005582661,0.00001875004,0.00008901589,0.9940354,0.0003001311,0.000119038,0.005190642],"study_design_scores_gemma":[0.000003169833,0.00005272767,0.00008022087,0.000001528933,0.000003919821,0.0001055212,0.000003161419,0.0002850113,0.998209,0.00002206015,0.00123165,0.0000020041],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7803507,0.009200624,0.1933996,0.0004627052,0.0003934362,0.0002639668,0.000361266,0.001193283,0.01437438],"genre_scores_gemma":[0.9223908,0.006428274,0.06207822,0.0001302157,0.00007209494,0.00007688671,0.0003061591,0.0001108819,0.008406519],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008355233,"threshold_uncertainty_score":0.00279516,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01926610253313101,"score_gpt":0.2159261765382681,"score_spread":0.1966600740051371,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}