{"id":"W2053681898","doi":"10.1002/marc.200400652","title":"Xanthate‐Mediated Living Radical Polymerization of Vinyl Acetate in Miniemulsion","year":2005,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":101,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Miniemulsion; Vinyl acetate; Xanthate; Polymer chemistry; Polymerization; Chain transfer; Raft; Reversible addition−fragmentation chain-transfer polymerization; Living polymerization; Chemistry; Radical polymerization; Monomer; Copolymer; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001723312,0.0003470291,0.0001294936,0.0001556025,0.00009190665,0.0002008293,0.0001574837,0.0001377409,0.001126303],"category_scores_gemma":[0.0001267652,0.00009859006,0.0001566848,0.00005757627,0.0001381667,0.0002702379,0.0001687824,0.0003081894,0.0003183994],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002351457,"about_ca_system_score_gemma":0.0001320233,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001614395,"about_ca_topic_score_gemma":0.0002358932,"domain_scores_codex":[0.9999419,0.000007750135,0.000004792914,0.0000146789,0.00001820272,0.00001257745],"domain_scores_gemma":[0.9999115,0.00001621954,0.00003423305,0.000008039123,0.00001215127,0.00001780982],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002275734,0.000004970548,0.00002314331,0.00002106533,0.000001894334,0.00001422452,0.000006994497,0.00004841979,0.9989805,0.00009459579,0.00001633813,0.0007651249],"study_design_scores_gemma":[0.000004263661,0.00005588543,0.0002031814,0.000001678748,0.000002386899,0.00002993352,0.000001422537,0.0004439589,0.9986934,0.00001345232,0.0005488542,0.000001519345],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889393,0.000831786,0.008293216,0.00005511976,0.00002749911,0.00002658984,0.0001149123,0.000168955,0.001542632],"genre_scores_gemma":[0.9890243,0.0004592536,0.005500488,0.00001673447,0.00001216392,0.00001909625,0.0001296509,0.00003049797,0.004807758],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001126303,"threshold_uncertainty_score":0.003767788,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0121003555244941,"score_gpt":0.2497204115592786,"score_spread":0.2376200560347845,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}