{"id":"W2054017627","doi":"10.1063/1.2166364","title":"Phosphodiester and N-glycosidic bond cleavage in DNA induced by 4–15 eV electrons","year":2006,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Canadian Institutes of Health Research","keywords":"Phosphodiester bond; Chemistry; Bond cleavage; Dissociation (chemistry); Glycosidic bond; Crystallography; Cleavage (geology); Excited state; Fragmentation (computing); Photochemistry; Organic chemistry; Atomic physics; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001458641,0.0003096082,0.0001782174,0.0002152973,0.000099086,0.0001544821,0.0002505775,0.0003865974,0.001199753],"category_scores_gemma":[0.0002395018,0.000183936,0.0002277925,0.0001610103,0.0002123651,0.0001597048,0.0001594789,0.0003127002,0.0001573954],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000235608,"about_ca_system_score_gemma":0.0001091949,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004150727,"about_ca_topic_score_gemma":0.0004820888,"domain_scores_codex":[0.9999034,0.00001701018,0.000004270228,0.00002012096,0.0000279788,0.00002706706],"domain_scores_gemma":[0.9998314,0.00007227893,0.00004318212,0.00001136697,0.00001877852,0.0000229346],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001167875,0.000007108556,0.0003311152,0.00003835351,0.00001160523,0.00007327246,0.00002647314,0.0001235988,0.9984119,0.00005811278,0.000006735793,0.0007948604],"study_design_scores_gemma":[0.00001062481,0.000205192,0.00427879,0.000005288417,0.00001017123,0.0001412295,0.00002079955,0.0004439551,0.9944437,0.00005293067,0.0003839767,0.00000327292],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998399,0.0004687619,0.0006945853,0.00001233257,0.000004565946,0.000005650394,0.00003776287,0.00001143133,0.0003660052],"genre_scores_gemma":[0.9975478,0.0002748759,0.001106701,0.00001485635,0.000002703593,0.000009260587,0.0001207372,0.00001010976,0.0009129649],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001199753,"threshold_uncertainty_score":0.004013598,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007127531702772901,"score_gpt":0.2317056404675318,"score_spread":0.2245781087647589,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}