{"id":"W2054082087","doi":"10.1021/ja710606v","title":"Facile and Selective Aliphatic C−H Bond Activation at Ambient Temperatures Initiated by Cp*W(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(η<sup>3</sup>-CH<sub>2</sub>CHCHMe)","year":2008,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Neopentane; Medicinal chemistry; Methylcyclohexane; Alkene; Adduct; Cyclohexene; Steric effects; Cyclopropane; Propene; Pyridine; Photochemistry; Stereochemistry; Molecule; Organic chemistry; Toluene; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006358582,0.0003960859,0.0001515714,0.00009236034,0.0001453073,0.0001579184,0.0002200304,0.000212438,0.001614521],"category_scores_gemma":[0.0001294918,0.0001329996,0.0001128413,0.0001127947,0.0001849949,0.0002484958,0.000295564,0.0003730534,0.0006509403],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001589853,"about_ca_system_score_gemma":0.0002317224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006506885,"about_ca_topic_score_gemma":0.001775206,"domain_scores_codex":[0.9999264,0.000003968367,0.000003277278,0.00002176298,0.00001818032,0.00002634328],"domain_scores_gemma":[0.9999492,0.00001033249,0.00001624659,0.000006874387,0.000007260523,0.00001012643],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007156722,0.00001249764,0.000158127,0.00006865474,0.000004594456,0.00002941208,0.00001557166,0.000083847,0.9964052,0.0001373028,0.0001111254,0.002901956],"study_design_scores_gemma":[0.000003881131,0.00005688745,0.0008693339,0.000002108517,0.00000306978,0.00005777403,0.000009334889,0.0002701448,0.9972926,0.0000316987,0.001399956,0.000003223978],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9844183,0.001057217,0.007578652,0.00006203083,0.00004753874,0.00005921604,0.0005738031,0.0001974518,0.006005837],"genre_scores_gemma":[0.993677,0.0005206573,0.002810128,0.00002416194,0.000005913311,0.00003670274,0.0003003745,0.0000320217,0.002593042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001614521,"threshold_uncertainty_score":0.005401075,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01001201856308084,"score_gpt":0.2130412155116435,"score_spread":0.2030291969485626,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}