{"id":"W2054082087","doi":"10.1021/ja710606v","title":"Facile and Selective Aliphatic C−H Bond Activation at Ambient Temperatures Initiated by Cp*W(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(η<sup>3</sup>-CH<sub>2</sub>CHCHMe)","year":2008,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Neopentane; Medicinal chemistry; Methylcyclohexane; Alkene; Adduct; Cyclohexene; Steric effects; Cyclopropane; Propene; Pyridine; Photochemistry; Stereochemistry; Molecule; Organic chemistry; Toluene; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004213939,0.0007806744,0.001372337,0.00008134496,0.0007372382,0.0001504527,0.000792944,0.0003147403,0.0001805927],"category_scores_gemma":[0.0005091205,0.0006188101,0.001362255,0.001101895,0.001148018,0.0004332786,0.0004797901,0.00136268,0.0000310752],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001161158,"about_ca_system_score_gemma":0.0002628599,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003663246,"about_ca_topic_score_gemma":0.000002125812,"domain_scores_codex":[0.9955646,0.0001668581,0.001245789,0.0008061424,0.001338219,0.0008783662],"domain_scores_gemma":[0.9958714,0.0006084498,0.001791789,0.0006928869,0.0005208374,0.0005146225],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002194892,0.0004546439,0.00125255,0.00008390148,0.001093621,0.00001179445,0.001184511,0.00003408805,0.9609821,0.000001677495,0.03199994,0.002681711],"study_design_scores_gemma":[0.001087689,0.0001160538,0.001561933,0.0001451794,0.0004246185,0.0003314132,0.0009143818,0.0003493079,0.9922144,0.00007149851,0.002067995,0.0007155],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979031,0.0004935971,0.00003440916,0.0008116795,0.00006716842,0.0001989483,0.0001646904,0.00008435342,0.0002420368],"genre_scores_gemma":[0.9963639,0.001588352,0.0001716596,0.001047743,0.0005143675,0.00003073639,0.00008198943,0.0001158727,0.00008536527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03123236,"threshold_uncertainty_score":0.9996263,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01001201856308084,"score_gpt":0.2130412155116435,"score_spread":0.2030291969485626,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}