{"id":"W2054146792","doi":"10.1021/jo010562g","title":"A Doubly Destabilized Antiaromatic Cyclopentadienyl Cation:  Solvolysis of a 5-Trifluoroacetoxy-5-heptafluoropropyl 1,3-Cyclopentadiene<sup>1</sup><sup>a</sup>","year":2001,"lang":"fr","type":"article","venue":"The Journal of Organic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Antiaromaticity; Solvolysis; Carbocation; Chemistry; Cyclopentadiene; Cyclopentadienyl complex; Medicinal chemistry; Reaction rate constant; Photochemistry; Organic chemistry; Kinetics; Aromaticity; Molecule; Hydrolysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001326041,0.000251336,0.0001730672,0.00008900095,0.0001724984,0.0001951813,0.0002698404,0.0003091956,0.00208595],"category_scores_gemma":[0.00018419,0.00007641627,0.0001385932,0.00007012556,0.0002516026,0.0002961823,0.0002394263,0.0002735975,0.0004665931],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002660811,"about_ca_system_score_gemma":0.000247459,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007077698,"about_ca_topic_score_gemma":0.0008273461,"domain_scores_codex":[0.9999053,0.00000829991,0.000003684243,0.000025795,0.00002097799,0.00003582894],"domain_scores_gemma":[0.9999204,0.00001678653,0.00002718297,0.000007527245,0.00001108305,0.0000170503],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003906902,0.00001454416,0.000265961,0.00005651169,0.00001038872,0.0001647064,0.00004278808,0.0002673868,0.9958677,0.0002008866,0.00009666281,0.002621719],"study_design_scores_gemma":[0.00002290268,0.0002775544,0.000764034,0.00000456609,0.000007279646,0.0002313294,0.00002798441,0.0005560955,0.9965031,0.00003450653,0.001562972,0.000007683516],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965694,0.0003557332,0.001335855,0.00004264955,0.00002152582,0.00001769211,0.0001143261,0.0000386047,0.001504196],"genre_scores_gemma":[0.9975501,0.000135281,0.000658139,0.00002189567,0.000004350745,0.000007961079,0.0001570351,0.00001202279,0.001453167],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00208595,"threshold_uncertainty_score":0.006978214,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03780577702183407,"score_gpt":0.3299737368063546,"score_spread":0.2921679597845205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}