{"id":"W2054194083","doi":"10.1021/tx6002968","title":"Near-UV Photolysis of 2-Methyl-1,4-naphthoquinone−DNA Duplexes:  Characterization of Reversible and Stable Interstrand Cross-Links between Quinone and Adenine Moieties","year":2007,"lang":"en","type":"article","venue":"Chemical Research in Toxicology","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Moiety; Chemistry; Deprotonation; Photodissociation; Radical; Protonation; DNA; Stereochemistry; Adduct; Photochemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001115536,0.0001430408,0.0003643264,0.0001174097,0.00004933701,0.00001906667,0.0002180774,0.0005602802,0.00004348296],"category_scores_gemma":[0.0003823334,0.0001452865,0.00004868727,0.0002599216,0.001407731,0.00001325105,0.0003523681,0.0004211954,5.155918e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002932471,"about_ca_system_score_gemma":0.00008167006,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000323235,"about_ca_topic_score_gemma":0.000006962228,"domain_scores_codex":[0.9983961,0.00007106635,0.0004498111,0.0004048502,0.0002282326,0.0004499416],"domain_scores_gemma":[0.999103,0.0001839139,0.0001163351,0.0002551945,0.0001832625,0.0001583313],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000544447,0.000089787,0.04376129,0.0002484247,0.00004463965,0.000006890898,0.0001483291,3.354814e-7,0.9539671,0.000008470941,0.00004140223,0.001138905],"study_design_scores_gemma":[0.0009543493,0.0003235371,0.01806619,0.00005053759,0.00001142222,0.00001054516,0.0001398897,0.00001411079,0.9795383,0.00007683926,0.0006953964,0.0001188958],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987568,0.0004298565,0.00007139683,0.0001382713,0.00002116318,0.0001645262,0.00004813595,0.000004538358,0.000365324],"genre_scores_gemma":[0.9986743,0.0004199069,0.000406457,0.00002022092,0.00007470993,0.000008983798,0.0001275016,0.00001693447,0.0002509502],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0256951,"threshold_uncertainty_score":0.592461,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03330331638753114,"score_gpt":0.353042451017448,"score_spread":0.3197391346299169,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}