{"id":"W2054208703","doi":"10.1021/ma9919054","title":"Solution Properties of Hydrophobically Modified Copolymers of <i>N</i>-Isopropylacrylamide and <i>N</i>-Glycine Acrylamide:  A Study by Microcalorimetry and Fluorescence Spectroscopy","year":2000,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Copolymer; Isothermal microcalorimetry; Poly(N-isopropylacrylamide); Polymer chemistry; Dynamic light scattering; Chemistry; Fluorescence spectroscopy; Polymer; Micelle; Aqueous solution; Acrylamide; Hydrodynamic radius; Lower critical solution temperature; Fluorescence; Materials science; Organic chemistry; Enthalpy; Nanoparticle; Thermodynamics; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002053942,0.0002888865,0.0003933091,0.0000629074,0.0001173956,0.00002564362,0.000260645,0.0001420715,0.00001595611],"category_scores_gemma":[0.00004417539,0.0002560369,0.00006466389,0.0001658246,0.0006912643,0.0000116835,0.0001537653,0.0001106218,0.000003010048],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001537782,"about_ca_system_score_gemma":0.00005940424,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005038136,"about_ca_topic_score_gemma":0.000033073,"domain_scores_codex":[0.9982283,0.0001226927,0.0005103494,0.0005923501,0.0002249871,0.0003213606],"domain_scores_gemma":[0.999146,0.00001139715,0.0001586016,0.0004932649,0.00008167325,0.0001090434],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004186208,0.0003986711,0.001470015,0.00008830283,0.0000929417,0.000001929277,0.0001906875,0.000006139005,0.9910746,0.000009724524,0.000129654,0.006118735],"study_design_scores_gemma":[0.0008491279,0.0007223323,0.0006342746,0.00004933764,0.00007206127,0.00002179305,0.0001861691,0.0002497605,0.9965569,0.00002826706,0.0003642186,0.0002657296],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9896755,0.00882104,0.0003252703,0.0001109694,0.00001659552,0.0006630701,0.00005411476,0.00002205235,0.0003114293],"genre_scores_gemma":[0.9972943,0.00133162,0.0009855608,0.00007072293,0.00002893714,0.00007567689,0.00002435973,0.00003894629,0.0001498986],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00761882,"threshold_uncertainty_score":0.9999892,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009053778020990748,"score_gpt":0.2215943119143201,"score_spread":0.2125405338933294,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}