{"id":"W2054208703","doi":"10.1021/ma9919054","title":"Solution Properties of Hydrophobically Modified Copolymers of <i>N</i>-Isopropylacrylamide and <i>N</i>-Glycine Acrylamide:  A Study by Microcalorimetry and Fluorescence Spectroscopy","year":2000,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Copolymer; Isothermal microcalorimetry; Poly(N-isopropylacrylamide); Polymer chemistry; Dynamic light scattering; Chemistry; Fluorescence spectroscopy; Polymer; Micelle; Aqueous solution; Acrylamide; Hydrodynamic radius; Lower critical solution temperature; Fluorescence; Materials science; Organic chemistry; Enthalpy; Nanoparticle; Thermodynamics; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001860293,0.0004253215,0.0002236252,0.0001351447,0.0001045282,0.0002080999,0.0001322268,0.000347063,0.0006319805],"category_scores_gemma":[0.0003555374,0.0001468217,0.0001633179,0.00009427086,0.0002097023,0.000252453,0.00009310908,0.0004480761,0.0002490544],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002122951,"about_ca_system_score_gemma":0.0001651514,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004504877,"about_ca_topic_score_gemma":0.0003182789,"domain_scores_codex":[0.9998609,0.00002015632,0.00000721594,0.00003516092,0.00005269871,0.0000238535],"domain_scores_gemma":[0.999786,0.0000567119,0.00007501015,0.00000892489,0.00004028113,0.00003314522],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002213399,0.000005655073,0.00005555628,0.00001130524,0.000001593302,0.000007354998,0.000007357608,0.0000214179,0.9995052,0.000008936289,0.000005102088,0.0003483877],"study_design_scores_gemma":[0.000006394857,0.0001372941,0.001086876,0.000002719512,0.000006330139,0.00004090514,0.000006583735,0.0004544861,0.9979649,0.000007050919,0.0002836334,0.000002973039],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949318,0.001091219,0.003053631,0.00005471646,0.00002643794,0.00001891264,0.00009775953,0.00005418399,0.0006713771],"genre_scores_gemma":[0.9936751,0.0008640729,0.003776713,0.00006505092,0.00002393021,0.00004066607,0.0002352079,0.00002728648,0.001292028],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006319805,"threshold_uncertainty_score":0.002114236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009053778020990748,"score_gpt":0.2215943119143201,"score_spread":0.2125405338933294,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}