{"id":"W2054247913","doi":"10.1021/ic801883e","title":"Donor−Acceptor Chemistry at Heavy Chalcogen Centers","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chalcogen; Acceptor; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000104534,0.0002786167,0.0004033264,0.00001228679,0.0001170638,0.00003056851,0.000231187,0.000177682,0.01089626],"category_scores_gemma":[0.0001083865,0.0002387753,0.0001927414,0.0001221064,0.00007661421,0.00004953575,0.00009633752,0.0002385688,0.0002767497],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002407166,"about_ca_system_score_gemma":0.0000838941,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001087558,"about_ca_topic_score_gemma":5.744049e-7,"domain_scores_codex":[0.9985101,0.00001173048,0.000345279,0.0004277786,0.0003051067,0.0003999768],"domain_scores_gemma":[0.9989174,0.00002469052,0.00009954622,0.0006127459,0.00006649739,0.0002790924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002041547,0.0001260771,0.001014235,0.0002051291,0.00005228236,0.00002133315,0.00007874725,1.86878e-7,0.9921502,0.000001753207,0.004665251,0.001480681],"study_design_scores_gemma":[0.000644908,0.00004316746,0.001901238,0.00007886648,0.0000689098,0.0003184402,0.00006607255,0.00001372887,0.9593961,0.00002801849,0.03719225,0.0002483145],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9393367,0.001563099,0.000005012046,0.001764827,0.00006800307,0.0001259884,0.00001456677,0.0001489794,0.05697284],"genre_scores_gemma":[0.9780378,0.0001028348,0.0001307488,0.0008966488,0.000537253,0.000006561235,0.00006831762,0.00003315941,0.02018666],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03870113,"threshold_uncertainty_score":0.9900079,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02101998603294461,"score_gpt":0.2373177499017847,"score_spread":0.2162977638688401,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}