{"id":"W2054247913","doi":"10.1021/ic801883e","title":"Donor−Acceptor Chemistry at Heavy Chalcogen Centers","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chalcogen; Acceptor; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001936316,0.000270009,0.0002967058,0.0001997147,0.0002481695,0.0005150167,0.0003644535,0.0001860453,0.001813951],"category_scores_gemma":[0.0001535637,0.0001213594,0.00009346785,0.0001504239,0.0002749987,0.0002259959,0.000348255,0.0002218968,0.0003964712],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004480471,"about_ca_system_score_gemma":0.0002645681,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003598824,"about_ca_topic_score_gemma":0.0006372043,"domain_scores_codex":[0.9998349,0.00004182242,0.00001031775,0.00003271846,0.00004358833,0.0000365037],"domain_scores_gemma":[0.9999338,0.00001112242,0.00001393485,0.00001531931,0.00001204715,0.0000137207],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003613627,0.00005468221,0.0004855368,0.0003172226,0.00002139071,0.0002631804,0.0001483976,0.0004929192,0.9764051,0.007858162,0.0005853314,0.01300661],"study_design_scores_gemma":[0.00004519475,0.0003533161,0.0002999432,0.000008759847,0.00001670582,0.0002589873,0.00002615516,0.0004789252,0.9920669,0.0002975415,0.006139431,0.000008148506],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9697884,0.002216212,0.008094053,0.0001461103,0.00003461609,0.00008617031,0.0002215884,0.0002529838,0.01915985],"genre_scores_gemma":[0.9938743,0.0006217936,0.002653521,0.00004638485,0.000005963409,0.00002212263,0.00006691838,0.00002049688,0.002688631],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001813951,"threshold_uncertainty_score":0.006068289,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02101998603294461,"score_gpt":0.2373177499017847,"score_spread":0.2162977638688401,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}