{"id":"W2054248544","doi":"10.1021/om8010323","title":"Fast Kinetic Studies of the Reactivities of Transient Germylenes in Methanol and Tetrahydrofuran Solution","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Methoxide; Tetrahydrofuran; Sodium methoxide; Flash photolysis; Protonation; Kinetic isotope effect; Methanol; Photochemistry; Reaction rate constant; Nitromethane; Quenching (fluorescence); Deprotonation; Medicinal chemistry; Solvent; Kinetics; Organic chemistry; Ion; Deuterium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001576713,0.0001898916,0.0004592719,0.0001262387,0.00005069403,0.00001306588,0.000227396,0.00008827876,0.0002490618],"category_scores_gemma":[0.0001229716,0.0001456682,0.0001005525,0.000440013,0.0002187059,0.0001165648,0.00005306259,0.0001139995,7.009031e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004780792,"about_ca_system_score_gemma":0.00003754436,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001476599,"about_ca_topic_score_gemma":0.00001608145,"domain_scores_codex":[0.9987879,0.00003614929,0.0005126285,0.0002287689,0.0002542702,0.0001802487],"domain_scores_gemma":[0.9991375,0.0001399561,0.0002686689,0.0003346922,0.0000850166,0.00003411748],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001454863,0.0001997863,0.001791802,0.000137545,0.00007179568,5.976844e-7,0.001760983,0.000004913142,0.9862679,0.0002834521,0.00000360346,0.009463136],"study_design_scores_gemma":[0.0004032588,0.00004726959,0.09353984,0.0001462553,0.00008774653,0.00001062038,0.001046598,0.00007136554,0.9034055,0.0003515039,0.0007033373,0.0001866828],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965729,0.001070099,0.00004662239,0.0006853548,0.00006115485,0.00007794728,0.00002000957,0.00001885619,0.00144711],"genre_scores_gemma":[0.9985117,0.0008022648,0.0001226788,0.00003477545,0.00003212127,0.000004066408,0.000005034116,0.00001768208,0.0004697199],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09174804,"threshold_uncertainty_score":0.5940178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02539727123247064,"score_gpt":0.2505265922173338,"score_spread":0.2251293209848632,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}