{"id":"W2054396575","doi":"10.1021/ja204767a","title":"A Reactive Ru–Binaphtholate Building Block with Self-Tuning Hapticity","year":2011,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ruthenium; Ligand (biochemistry); Acetonitrile; Moiety; Pyridine; Metal; Crystallography; Stereochemistry; Medicinal chemistry; Catalysis; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009726972,0.0002906637,0.0002622493,0.0001577867,0.0001698977,0.0002864643,0.0006602461,0.0002466716,0.00190822],"category_scores_gemma":[0.0001043226,0.0001624065,0.0001252902,0.0001547961,0.0002247993,0.0002945527,0.0004756128,0.0005235156,0.000727758],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002970494,"about_ca_system_score_gemma":0.0002519894,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005955118,"about_ca_topic_score_gemma":0.001149707,"domain_scores_codex":[0.9999298,0.00000798645,0.000004042276,0.00001747155,0.00002137524,0.0000193263],"domain_scores_gemma":[0.9999446,0.000007850012,0.00001199057,0.000006488478,0.000004952215,0.00002405808],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001676494,0.00008263977,0.0002097904,0.0001566974,0.00001790011,0.0002111504,0.00004297783,0.001526175,0.977281,0.004470013,0.0002577364,0.01557622],"study_design_scores_gemma":[0.00008164567,0.0008687677,0.0008405118,0.0000142272,0.00003374945,0.0003978634,0.0000214569,0.007002024,0.9648669,0.0004691977,0.02534925,0.00005440067],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9491929,0.002178872,0.03591505,0.0001665923,0.000131445,0.00016623,0.0003297042,0.0009277915,0.01099145],"genre_scores_gemma":[0.9667623,0.001040706,0.02533138,0.00008160557,0.00001551569,0.000107499,0.0002831528,0.00005563616,0.006322052],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00190822,"threshold_uncertainty_score":0.006383598,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01815475921629382,"score_gpt":0.2582578487174088,"score_spread":0.240103089501115,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}