{"id":"W2054451094","doi":"10.1016/j.freeradbiomed.2010.05.029","title":"Characterization and detection in cells of a novel adduct derived from the conjugation of glutathione and dehydroascorbate","year":2010,"lang":"en","type":"article","venue":"Free Radical Biology and Medicine","topic":"Vitamin C and Antioxidants Research","field":"Nursing","cited_by":20,"is_retracted":false,"has_abstract":false,"ca_institutions":"Health and Social Services Centre University Institute of Geriatrics of Sherbrooke; Université de Sherbrooke","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; Glutathione; Ascorbic acid; Dehydroascorbic acid; Cysteine; Adduct; Biochemistry; Antioxidant; Moiety; Phenylhydrazine; Tandem mass spectrometry; Reactive oxygen species; Reactive intermediate; Stereochemistry; Vitamin C; Mass spectrometry; Chromatography; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002442209,0.000413551,0.0002635462,0.0002922523,0.0002138926,0.0002970432,0.0003014783,0.0006120326,0.0009898437],"category_scores_gemma":[0.0002035449,0.0002451567,0.0003742165,0.0002295268,0.0002341751,0.0003139006,0.0003012691,0.000531322,0.0005942443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002034405,"about_ca_system_score_gemma":0.0002430965,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000519947,"about_ca_topic_score_gemma":0.0004654038,"domain_scores_codex":[0.9998927,0.00002023207,0.000007199081,0.00003160137,0.00002899078,0.00001931217],"domain_scores_gemma":[0.9997858,0.00004370719,0.00003927607,0.00004536562,0.0000546005,0.00003116724],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005379993,0.0000141051,0.0002156655,0.00001239384,0.00000523898,0.00003622537,0.00002237459,0.00001430264,0.9989935,0.00006380041,0.0000108252,0.0005577737],"study_design_scores_gemma":[0.00001263812,0.0002758093,0.003594753,0.000002518957,0.00001890142,0.000255808,0.00004438136,0.0003818372,0.994259,0.00006417862,0.001086119,0.000004091424],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.966098,0.001388576,0.0302641,0.0001682122,0.00006244464,0.0000791984,0.0004796844,0.000127731,0.001332157],"genre_scores_gemma":[0.9816222,0.0005527764,0.01318522,0.00006684715,0.00001484684,0.00006017991,0.0009904704,0.00002306508,0.003484479],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009898437,"threshold_uncertainty_score":0.003311396,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01530454039198261,"score_gpt":0.2836134440172381,"score_spread":0.2683089036252555,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}