{"id":"W2054451094","doi":"10.1016/j.freeradbiomed.2010.05.029","title":"Characterization and detection in cells of a novel adduct derived from the conjugation of glutathione and dehydroascorbate","year":2010,"lang":"en","type":"article","venue":"Free Radical Biology and Medicine","topic":"Vitamin C and Antioxidants Research","field":"Nursing","cited_by":20,"is_retracted":false,"has_abstract":false,"ca_institutions":"Health and Social Services Centre University Institute of Geriatrics of Sherbrooke; Université de Sherbrooke","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; Glutathione; Ascorbic acid; Dehydroascorbic acid; Cysteine; Adduct; Biochemistry; Antioxidant; Moiety; Phenylhydrazine; Tandem mass spectrometry; Reactive oxygen species; Reactive intermediate; Stereochemistry; Vitamin C; Mass spectrometry; Chromatography; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002945431,0.00005717429,0.000171723,0.0000535881,0.00004410543,0.000001915489,0.00004591471,0.0001187466,0.00001568255],"category_scores_gemma":[0.0003939841,0.00003530247,0.000007089418,0.00008042441,0.0009095873,0.00003507574,0.00002669231,0.0001820131,1.287086e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000002481348,"about_ca_system_score_gemma":0.000006563837,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003204855,"about_ca_topic_score_gemma":0.0002367545,"domain_scores_codex":[0.9994784,0.00006940601,0.0001803231,0.0001302978,0.00005549368,0.00008606714],"domain_scores_gemma":[0.9994793,0.000295589,0.00007591506,0.00008369613,0.00002562735,0.00003989917],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0001431705,0.00002691122,0.007990958,0.0000212085,0.000007028563,3.701835e-7,0.000712621,2.990843e-8,0.9489495,0.0001072582,0.000003424421,0.04203752],"study_design_scores_gemma":[0.002496057,0.0004234535,0.5060697,0.0001159905,0.00002490591,0.00001170737,0.0001581928,0.00128234,0.488512,0.0006492495,0.0002081981,0.00004815574],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995856,0.0003142554,0.001511119,0.001931984,0.0002107952,0.0001345547,0.00002893042,0.000004296675,0.000008079349],"genre_scores_gemma":[0.9992812,0.0003470408,0.0001284236,0.0001024543,0.0000997704,0.000002622327,0.00003118313,0.000003313833,0.000004038973],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4980788,"threshold_uncertainty_score":0.3351412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01530454039198261,"score_gpt":0.2836134440172381,"score_spread":0.2683089036252555,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}