{"id":"W2054485881","doi":"10.1039/b714383d","title":"Electrochemical detection of kinase-catalyzed phosphorylation using ferrocene-conjugated ATP","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":106,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Conjugated system; Ferrocene; Catalysis; Electrochemistry; Phosphorylation; Kinase; Chemistry; Adenosine triphosphate; Combinatorial chemistry; Biochemistry; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00036547,0.0005680753,0.000407301,0.000253838,0.0002429019,0.0004387129,0.0009616764,0.001037949,0.00125178],"category_scores_gemma":[0.0004968091,0.0003020137,0.0001426462,0.0003350647,0.0003634991,0.00040383,0.0002680424,0.0009315156,0.0003937345],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006390066,"about_ca_system_score_gemma":0.0002816273,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008238064,"about_ca_topic_score_gemma":0.001217195,"domain_scores_codex":[0.9996157,0.00006429,0.00001685394,0.000118642,0.0001126092,0.00007191458],"domain_scores_gemma":[0.9997562,0.0001136675,0.00003277947,0.00001664435,0.00004604176,0.00003479507],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003762193,0.00001620469,0.00006488626,0.00003068355,0.000003414968,0.00003807557,0.00002172116,0.00004957837,0.9980345,0.000100558,0.0000596785,0.001542938],"study_design_scores_gemma":[0.000007513919,0.00004000312,0.0003329864,0.000003068949,0.000003802277,0.0001164533,0.00001345878,0.001299085,0.9978113,0.00003816356,0.0003306404,0.000003583581],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9694493,0.001643022,0.02427014,0.0004621573,0.0001547026,0.00004596926,0.000283121,0.0004196626,0.003271952],"genre_scores_gemma":[0.9798006,0.00129139,0.01567758,0.0001291539,0.00002967316,0.00004403,0.0002587647,0.00002470309,0.00274399],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00125178,"threshold_uncertainty_score":0.004636347,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02078577520337728,"score_gpt":0.3008174111427131,"score_spread":0.2800316359393358,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}