{"id":"W2054596687","doi":"10.1002/chin.200002039","title":"ChemInform Abstract: Rate Constants for 5‐Exo Secondary Alkyl Radical Cyclizations onto Hydrazones and Oxime Ethers via Intramolecular Competition Experiments.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Intramolecular force; Oxime; Competition (biology); Alkyl; Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001371072,0.0003987976,0.0004023399,0.00004579625,0.000255639,0.0001071622,0.0002831024,0.0004362974,0.02396244],"category_scores_gemma":[0.0001702014,0.0004151633,0.0001822969,0.0001238867,0.0005628486,0.0004503784,0.0000490497,0.0004432617,0.0001188688],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002625166,"about_ca_system_score_gemma":0.0001353883,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007082398,"about_ca_topic_score_gemma":0.000006065778,"domain_scores_codex":[0.997985,2.284244e-7,0.0006843995,0.0004476595,0.0003035261,0.000579179],"domain_scores_gemma":[0.9985415,0.0002698016,0.0001769845,0.0004380381,0.00008246222,0.0004912482],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002142509,0.0002163598,0.000008359246,0.0002655356,0.00014991,0.000008524366,0.0004899893,0.000001820029,0.7292812,0.0004557314,0.01026606,0.2586422],"study_design_scores_gemma":[0.001548756,0.00002005006,0.00004456683,0.00008836218,0.0000502086,0.00004649554,0.0001773679,0.0002390268,0.7850454,0.000741423,0.2115861,0.000412243],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.124962,0.0003397569,0.0000174001,0.0002343691,0.00006508867,0.0004475265,0.0001860279,0.0002348974,0.8735129],"genre_scores_gemma":[0.9808088,0.0002785938,0.0002824078,0.000798829,0.0002281129,0.0004855828,0.001369945,0.00008971419,0.01565802],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8578549,"threshold_uncertainty_score":0.99983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01051164211062679,"score_gpt":0.2523069461519938,"score_spread":0.241795304041367,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}