{"id":"W2054865930","doi":"10.1021/ic7012182","title":"Formation of a Phosphine−phosphinite Ligand in RhCl(PRR‘<sub>2</sub>)[<i>P</i>,<i>P</i>-R‘(R)POCH<sub>2</sub>P(CH<sub>2</sub>OH)<sub>2</sub>] and R‘H from <i>cis</i>-RhCl(PRR‘<sub>2</sub>)<sub>2</sub>[P(CH<sub>2</sub>OH)<sub>3</sub>] via P−C Bond Cleavage","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Phosphinite; Phosphine; Ligand (biochemistry); Combinatorics; Mathematics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001213004,0.0002679619,0.0002148021,0.000075403,0.0001466132,0.0002624216,0.0004653805,0.000337673,0.002373397],"category_scores_gemma":[0.0001773875,0.0002199664,0.0001536975,0.00007979968,0.0001867594,0.0002687633,0.0003368054,0.000488645,0.0008201755],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003321281,"about_ca_system_score_gemma":0.0003117887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001013975,"about_ca_topic_score_gemma":0.001301348,"domain_scores_codex":[0.9998587,0.00002332828,0.000009017918,0.00003995783,0.00003618873,0.00003270015],"domain_scores_gemma":[0.9999465,0.0000118632,0.00001467454,0.000009540066,0.00000608947,0.00001138642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00023506,0.00002376248,0.00009095678,0.0001849924,0.000008384131,0.0001441485,0.00008227627,0.0002608975,0.9963627,0.0006681745,0.0002194821,0.00171917],"study_design_scores_gemma":[0.00002733823,0.0001716621,0.0001940492,0.000005034001,0.000006640214,0.0001620393,0.00001558191,0.0008041095,0.9962389,0.00003791074,0.002329186,0.000007434304],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9822915,0.0006759258,0.005736568,0.0001507241,0.00005997244,0.0001341368,0.0003738221,0.0003799419,0.01019734],"genre_scores_gemma":[0.9930981,0.0001777053,0.002049288,0.00004387245,0.000006216198,0.00003992534,0.0002286596,0.00003955118,0.004316648],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002373397,"threshold_uncertainty_score":0.007939816,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005561853709648391,"score_gpt":0.1994159222334702,"score_spread":0.1938540685238218,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}