{"id":"W2054907253","doi":"10.1021/om020220g","title":"Novel Blue Phosphorescent Group 15 Compounds MR<sub>3</sub> (M = P, Sb, Bi; R = <i>p</i>-(<i>N</i>-7-Azaindolyl)phenyl)","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Phosphorescence; Chemistry; Crystallography; Lone pair; Trigonal bipyramidal molecular geometry; Ligand (biochemistry); Luminescence; Crystal structure; Atom (system on chip); Bond length; Fluorescence; Molecule; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007619753,0.0002923191,0.0002101767,0.0001283427,0.0001139694,0.0003469518,0.0003547969,0.0002150574,0.0009675988],"category_scores_gemma":[0.00006548543,0.000118953,0.0001361139,0.0001150067,0.0002292421,0.0002212231,0.0002537148,0.0001924597,0.0003771362],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003583692,"about_ca_system_score_gemma":0.0002087762,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000527001,"about_ca_topic_score_gemma":0.001040775,"domain_scores_codex":[0.999935,0.000008661066,0.000004792076,0.00001291373,0.00002151089,0.00001719478],"domain_scores_gemma":[0.9999564,0.00000358806,0.00001595468,0.000003268964,0.000006387509,0.00001430661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001112595,0.00001588919,0.0001132776,0.0001028311,0.00001201799,0.00005332232,0.00004024128,0.0001938023,0.9955636,0.0005519029,0.0001110398,0.003130866],"study_design_scores_gemma":[0.00005293941,0.0003618941,0.0006569368,0.000007218332,0.0000252473,0.000202468,0.00002890297,0.0007609729,0.9904394,0.00009332682,0.007358502,0.00001219111],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878982,0.001953385,0.00470686,0.00006892878,0.00002352657,0.00003347488,0.0002143403,0.0002765573,0.004824685],"genre_scores_gemma":[0.9852534,0.0009672269,0.008650134,0.00007592839,0.000007561344,0.00003497277,0.0002553043,0.00004954929,0.004706067],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009675988,"threshold_uncertainty_score":0.00323689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01592381480595494,"score_gpt":0.199266907963237,"score_spread":0.183343093157282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}