{"id":"W2054907253","doi":"10.1021/om020220g","title":"Novel Blue Phosphorescent Group 15 Compounds MR<sub>3</sub> (M = P, Sb, Bi; R = <i>p</i>-(<i>N</i>-7-Azaindolyl)phenyl)","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Phosphorescence; Chemistry; Crystallography; Lone pair; Trigonal bipyramidal molecular geometry; Ligand (biochemistry); Luminescence; Crystal structure; Atom (system on chip); Bond length; Fluorescence; Molecule; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0005283618,0.0007479668,0.0007420925,0.0004040862,0.0002750289,0.000335288,0.001115371,0.000394638,0.001093768],"category_scores_gemma":[0.00017529,0.0007874526,0.0002866726,0.001875919,0.0002263607,0.000410845,0.0003776907,0.001046514,0.002470568],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005874129,"about_ca_system_score_gemma":0.00004226213,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001934909,"about_ca_topic_score_gemma":0.00003661387,"domain_scores_codex":[0.995615,0.00007117385,0.0008403388,0.0008160016,0.001143559,0.001513891],"domain_scores_gemma":[0.9976122,0.0002344688,0.0001181343,0.001281518,0.0001531672,0.0006004618],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001159685,0.0005051301,0.0005493685,0.0002100952,0.0002912026,0.00004889988,0.0007875374,0.0001898015,0.9830391,0.0005903599,0.01110704,0.002669882],"study_design_scores_gemma":[0.001746874,0.0001286659,0.000721539,0.0000801084,0.00009409289,0.0001051996,0.0001349505,0.01663627,0.8973992,0.00002584852,0.08173243,0.001194853],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9792178,0.004096199,0.005564916,0.0003943257,0.001523126,0.0007796976,0.0001183641,0.001708672,0.006596865],"genre_scores_gemma":[0.994292,0.001649114,0.002079235,0.00029861,0.0006159084,0.00004953221,0.00007756468,0.0004087216,0.0005292966],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08563992,"threshold_uncertainty_score":0.9998193,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01592381480595494,"score_gpt":0.199266907963237,"score_spread":0.183343093157282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}