{"id":"W2054975654","doi":"10.1002/cbic.201100204","title":"Bis‐Azobenzene Crosslinkers for Photocontrol of Peptide Structure","year":2011,"lang":"en","type":"article","venue":"ChemBioChem","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"National Institute of Mental Health; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; National Institutes of Health","keywords":"Photoswitch; Azobenzene; Photoisomerization; Chemistry; Isomerization; Helix (gastropod); Peptide; Photochromism; Biomolecule; Spiropyran; Stereochemistry; Photochemistry; Molecule; Organic chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001207623,0.0003698157,0.0001941313,0.0001300221,0.0001143846,0.0002163864,0.0002663173,0.000296533,0.00140405],"category_scores_gemma":[0.0001233973,0.0001380203,0.0001817684,0.0001721986,0.0001857225,0.0002547418,0.0001692545,0.000526139,0.000385281],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003022899,"about_ca_system_score_gemma":0.00009010666,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003310592,"about_ca_topic_score_gemma":0.0006355492,"domain_scores_codex":[0.9998955,0.0000174533,0.000006537551,0.00002772127,0.00003449422,0.0000183383],"domain_scores_gemma":[0.9999121,0.00002183387,0.00003101993,0.000005953198,0.000009713737,0.00001946613],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001419906,0.000005567973,0.000033261,0.00002829358,0.000002789537,0.00001231623,0.00000527501,0.00007290898,0.9985275,0.00008100399,0.00001283573,0.001204032],"study_design_scores_gemma":[0.000006441977,0.0001191578,0.0005799992,0.000003494385,0.000009067299,0.0001067172,0.000005130406,0.0006007957,0.9960604,0.00004899543,0.002456079,0.000003781348],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9346308,0.01367878,0.04716849,0.0001696162,0.00009293625,0.00009872193,0.0003084329,0.0002768867,0.003575438],"genre_scores_gemma":[0.9685996,0.004251727,0.02413955,0.00009191327,0.00002620222,0.00005448615,0.0004051416,0.0000385946,0.002392845],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00140405,"threshold_uncertainty_score":0.004697025,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02379981046809692,"score_gpt":0.234928415127929,"score_spread":0.2111286046598321,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}