{"id":"W2055061141","doi":"10.1006/jcht.2002.0937","title":"Thermodynamics of aqueous amines: excess molar heat capacities, volumes, and expansibilities of {water+ methyldiethanolamine (MDEA)} and {water + 2-amino-2-methyl-1-propanol (AMP)}","year":2002,"lang":"en","type":"article","venue":"The Journal of Chemical Thermodynamics","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":67,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph; St. Francis Xavier University; Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Mole fraction; Aqueous solution; Calorimeter (particle physics); Thermodynamics; Excess heat; Dilution; Molar; Enthalpy; Partial molar property; Heat capacity; Analytical Chemistry (journal); Chromatography; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003201755,0.0002684864,0.0002117761,0.0003775332,0.0001730082,0.0003851967,0.0003430317,0.0002087314,0.001844319],"category_scores_gemma":[0.0008553719,0.0002216777,0.0001303662,0.0001547644,0.0005662887,0.0008255989,0.0003378736,0.0004020883,0.000365309],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003403098,"about_ca_system_score_gemma":0.0001528887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005180467,"about_ca_topic_score_gemma":0.0006304519,"domain_scores_codex":[0.9998727,0.00001722179,0.000007692348,0.00003190133,0.00004560033,0.00002477446],"domain_scores_gemma":[0.999742,0.0001326698,0.00004466293,0.00001394457,0.00003614435,0.0000306241],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006680783,0.00006274934,0.004135497,0.0001727134,0.00003434029,0.0001069524,0.0001674066,0.0076199,0.9725505,0.00683331,0.0002057896,0.007442866],"study_design_scores_gemma":[0.00001945605,0.0001882957,0.005273514,0.000007650861,0.00001727059,0.00009695435,0.00006471246,0.03741466,0.9545205,0.001502523,0.0008741513,0.00002024932],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965826,0.0005530809,0.001504607,0.00005087686,0.00001104113,0.000005432431,0.00009377841,0.00002504957,0.001173592],"genre_scores_gemma":[0.998754,0.0002397913,0.0002588271,0.000009682787,0.000009770809,0.000006373528,0.00009890337,0.000008974548,0.0006136243],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001844319,"threshold_uncertainty_score":0.006169856,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0139739169504222,"score_gpt":0.2058025537688191,"score_spread":0.1918286368183969,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}