{"id":"W2055064297","doi":"10.1021/jo000029l","title":"Synthesis of Phytyl- and Chroman-Derivatized Photoaffinity Labels Based on α-Tocopherol","year":2000,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Antioxidant Activity and Oxidative Stress","field":"Medicine","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Silylation; Wittig reaction; Alkyl; Trolox; Side chain; Organic chemistry; Aldehyde; Stereochemistry; Catalysis; Antioxidant","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001143811,0.0004683739,0.0003300401,0.0002236355,0.0001859355,0.0002278518,0.000383414,0.0004689285,0.00225053],"category_scores_gemma":[0.0001356682,0.0002746272,0.0002849596,0.0002483797,0.0001502642,0.0002589863,0.0002681799,0.0005961913,0.001562372],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000533526,"about_ca_system_score_gemma":0.0002861319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007917771,"about_ca_topic_score_gemma":0.001724887,"domain_scores_codex":[0.9998896,0.00001065926,0.000006143991,0.00003558985,0.00002218128,0.00003576795],"domain_scores_gemma":[0.999876,0.00001621847,0.00003109208,0.00002067122,0.00002103703,0.0000349623],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003729807,0.000009402178,0.00004543387,0.00003235822,0.000004104011,0.00004002598,0.000009263175,0.00005516137,0.9983083,0.00009467254,0.00003334054,0.001330751],"study_design_scores_gemma":[0.000008874511,0.00008195148,0.0005405312,0.00000280899,0.000008536805,0.00007101041,0.00000575285,0.000167723,0.9954659,0.00002154439,0.003619352,0.000006020965],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9691389,0.002499039,0.02038054,0.0001367809,0.0001125982,0.0001816688,0.0008044746,0.0004306899,0.006315352],"genre_scores_gemma":[0.951608,0.002380784,0.02707725,0.0002462696,0.0000352717,0.0001895562,0.001361138,0.00009388454,0.01700781],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00225053,"threshold_uncertainty_score":0.007528722,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009355357145547003,"score_gpt":0.234807172649034,"score_spread":0.225451815503487,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}