{"id":"W2055351389","doi":"10.1039/b604150g","title":"Reactivity of electrophilic μ-phosphinidene complexes with N-heterocyclic carbenes: formation of the first main group element adducts of ‘abnormal’ carbene ligands","year":2006,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Steacie Institute for Molecular Sciences","funders":"","keywords":"Phosphinidene; Carbene; Electrophile; Adduct; Chemistry; Reactivity (psychology); Main group element; Group (periodic table); Medicinal chemistry; Stereochemistry; Organic chemistry; Transition metal; Catalysis; Medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001776079,0.0002839594,0.0001675823,0.0001380427,0.0001696199,0.0003710664,0.0004260655,0.0002735388,0.001881285],"category_scores_gemma":[0.0003350376,0.0001830445,0.00009849215,0.0001301276,0.0003145774,0.0002849259,0.0002853264,0.0002902793,0.0002842073],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003933348,"about_ca_system_score_gemma":0.0001118067,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001054542,"about_ca_topic_score_gemma":0.00136283,"domain_scores_codex":[0.999818,0.0000324882,0.000009872685,0.0000435935,0.00004999988,0.00004596029],"domain_scores_gemma":[0.9998451,0.00003496262,0.00003491298,0.00002555099,0.00001843927,0.00004097451],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003628148,0.00002835544,0.000900741,0.00007128925,0.00002629878,0.0002039018,0.0001336016,0.0004650647,0.9953419,0.0006184079,0.0001015971,0.001745947],"study_design_scores_gemma":[0.00001117391,0.00008666705,0.001030693,0.000002353185,0.000006758296,0.0001978157,0.00002001411,0.0004154588,0.9972312,0.00003793923,0.0009549796,0.000004916878],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959919,0.0002868077,0.0007220316,0.00002178256,0.000005343974,0.000009197964,0.00005251115,0.00003949333,0.002871098],"genre_scores_gemma":[0.9986309,0.00006809752,0.0002723932,0.00000847263,0.000001696112,0.000004556644,0.00007217618,0.000007799504,0.0009339299],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001881285,"threshold_uncertainty_score":0.006293476,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01333401480893983,"score_gpt":0.211551170029299,"score_spread":0.1982171552203591,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}