{"id":"W2055445566","doi":"10.1021/ma060411l","title":"High-Temperature Free Radical Copolymerization of Styrene and Butyl Methacrylate with Depropagation and Penultimate Kinetic Effects","year":2006,"lang":"en","type":"article","venue":"Macromolecules","topic":"Photopolymerization techniques and applications","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Copolymer; Polymer chemistry; Monomer; Methacrylate; Styrene; Chemistry; Reactivity (psychology); Polymerization; Solvent; Kinetics; Methyl methacrylate; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003404841,0.0001494772,0.0001863261,0.00004458752,0.00008623556,0.00004054651,0.00008883725,0.0000975636,0.00004092982],"category_scores_gemma":[0.00001679568,0.0001294233,0.00001706958,0.0001424187,0.0001806829,0.00005422625,0.00004937697,0.00008073174,4.557373e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000008869625,"about_ca_system_score_gemma":0.000013645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003173955,"about_ca_topic_score_gemma":0.00001470115,"domain_scores_codex":[0.9992685,0.00001915117,0.0001943134,0.0002507798,0.0001391138,0.0001281648],"domain_scores_gemma":[0.9995086,0.00003977391,0.0001293595,0.0002333575,0.00003984568,0.00004903434],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002176036,0.00004219087,0.0006072434,0.0001713558,0.00001217496,0.000004391014,0.00002469866,0.00001080648,0.9940789,0.003703441,0.00002745882,0.001295523],"study_design_scores_gemma":[0.0006644395,0.00004407469,0.001922898,0.00007399345,0.00004623423,0.00002512844,0.00001149664,0.0003489664,0.9952137,0.001449029,0.00005256185,0.0001474675],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927048,0.0006562285,0.005820866,0.0001128911,0.000007323861,0.0001534349,0.00007820281,0.0001018194,0.000364405],"genre_scores_gemma":[0.9914314,0.00009444035,0.008045367,0.00002969229,0.00002882195,0.00006329806,0.000196186,0.00002589298,0.00008497317],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002254411,"threshold_uncertainty_score":0.527773,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00195209011878515,"score_gpt":0.1895287226752304,"score_spread":0.1875766325564452,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}