{"id":"W2055620942","doi":"10.1039/c0an00584c","title":"A new form of analytical chemistry: distinguishing the molecular structure of photo-induced states from ground-states","year":2010,"lang":"en","type":"article","venue":"The Analyst","topic":"X-ray Spectroscopy and Fluorescence Analysis","field":"Physics and Astronomy","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Royal Society","keywords":"Context (archaeology); Synchrotron; Diffraction; Field (mathematics); Resolution (logic); Laser; Chemistry; Synchrotron radiation; Sample (material); Optics; Engineering physics; Nanotechnology; Computational physics; Computer science; Physics; Materials science; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001216728,0.0004844183,0.0006780237,0.001918901,0.001363098,0.003139426,0.001694352,0.001796697,0.003077929],"category_scores_gemma":[0.002904344,0.0004921212,0.0005050356,0.0008801462,0.008412643,0.005430717,0.001940164,0.00433202,0.001114101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008252949,"about_ca_system_score_gemma":0.0009893709,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003586857,"about_ca_topic_score_gemma":0.0005434663,"domain_scores_codex":[0.9990276,0.0002027306,0.00004471286,0.000293133,0.0003713668,0.00006048692],"domain_scores_gemma":[0.9980363,0.001062776,0.0002576158,0.0004090239,0.0001536535,0.00008065496],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001686428,0.0001175306,0.001301005,0.0009974806,0.00006238625,0.0002841394,0.001253213,0.0008553363,0.2055189,0.6751807,0.004996739,0.1092641],"study_design_scores_gemma":[0.00005058201,0.000479331,0.001642331,0.0002659175,0.00006127397,0.002871202,0.0009600184,0.01033909,0.2473003,0.5353686,0.2004918,0.0001695579],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.04486345,0.03038786,0.8637667,0.007304424,0.002027779,0.0001364344,0.0005249148,0.001439807,0.04954861],"genre_scores_gemma":[0.4111414,0.01872569,0.5469046,0.004532528,0.001663263,0.0003516786,0.0003051991,0.0003957809,0.01597982],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.003139426,"threshold_uncertainty_score":0.0102967,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005111409592297262,"score_gpt":0.2414778063287556,"score_spread":0.2363663967364583,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}