{"id":"W2055695306","doi":"10.1021/ja201143v","title":"Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies","year":2011,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":931,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Rhodium; Catalysis; Catalytic cycle; Deprotonation; Reactivity (psychology); Reductive elimination; Oxidative addition; Combinatorial chemistry; Metalation; Limiting; Redox; Photochemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000548255,0.0002027585,0.0005241208,0.0000195111,0.0001361315,0.0000318423,0.0003834981,0.00006564546,0.0000878035],"category_scores_gemma":[0.0008342612,0.0001441631,0.0003988803,0.0001682401,0.0005809817,0.0001967859,0.0002747292,0.0003958813,4.715693e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003361386,"about_ca_system_score_gemma":0.00006691441,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002285091,"about_ca_topic_score_gemma":0.000002096277,"domain_scores_codex":[0.998668,0.00006788764,0.0004842428,0.0002365552,0.0003215222,0.000221793],"domain_scores_gemma":[0.9978226,0.000387762,0.001112681,0.000320098,0.0002048553,0.0001519818],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001914077,0.0001437403,0.0004773249,0.00004129571,0.0003711851,0.000002763876,0.0008842265,0.000002673042,0.9948748,0.000007653464,0.00005240507,0.002950515],"study_design_scores_gemma":[0.0003898081,0.00002241386,0.0004242709,0.00008653696,0.0003327427,0.000422759,0.00237565,0.002381932,0.9926901,0.0006433922,0.00004690979,0.0001834373],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922112,0.00009738442,0.007324075,0.00008650379,0.0001366007,0.00003486063,0.00001067473,0.00002033139,0.00007835209],"genre_scores_gemma":[0.9756084,0.00008021607,0.02383904,0.0001379911,0.000269514,0.000003223446,7.449169e-7,0.00002768911,0.0000331913],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01660282,"threshold_uncertainty_score":0.5878801,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05491532914920607,"score_gpt":0.3133182793492177,"score_spread":0.2584029502000116,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}