{"id":"W2055701496","doi":"10.1002/anie.200250780","title":"[Co(CO)<sub>5</sub>][(CF<sub>3</sub>)<sub>3</sub>BF]: A Stable Salt of a Homoleptic Trigonal‐Bipyramidal Metal–Carbonyl Cation","year":2003,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Homoleptic; Superacid; Oxidizing agent; Anhydrous; Chemistry; Salt (chemistry); Trigonal bipyramidal molecular geometry; Cobalt; Cyan; Inorganic chemistry; Metal; Transition metal; Crystallography; Photochemistry; Catalysis; Crystal structure; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006029024,0.0001998577,0.0001625275,0.0001411756,0.0002009373,0.0003113523,0.0002486565,0.0002159101,0.00284186],"category_scores_gemma":[0.0001219143,0.0000986162,0.00006249487,0.0001944003,0.0001836756,0.0001718732,0.000188592,0.0001734103,0.0005932277],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003729593,"about_ca_system_score_gemma":0.0002444774,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002916479,"about_ca_topic_score_gemma":0.004199894,"domain_scores_codex":[0.9999418,0.0000055698,0.000003320283,0.000009843558,0.00001821321,0.00002116467],"domain_scores_gemma":[0.9999515,0.000003718736,0.00001200464,0.00000543599,0.00001027406,0.00001706996],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003298486,0.00002409288,0.0003908578,0.0001899894,0.00001273622,0.0002254515,0.00004489088,0.0001854885,0.9918513,0.001528398,0.0009769866,0.004239888],"study_design_scores_gemma":[0.00006300562,0.0002602927,0.00250117,0.00001208366,0.00001912971,0.0004348619,0.00004504522,0.0008527713,0.9807381,0.0001799731,0.0148806,0.000012879],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9820258,0.0004960867,0.00275342,0.0001786701,0.00008309812,0.00003422417,0.0002526115,0.0003391942,0.01383678],"genre_scores_gemma":[0.9927115,0.0002285932,0.001696045,0.00003982551,0.00001009962,0.000008543172,0.0002523741,0.00004833827,0.005004631],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002916479,"threshold_uncertainty_score":0.009506941,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01094207275312892,"score_gpt":0.2381849931298818,"score_spread":0.2272429203767528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}