{"id":"W2055934028","doi":"10.1016/j.jchromb.2012.10.044","title":"A highly sensitive capillary electrophoresis method using p-nitrophenyl 5′-thymidine monophosphate as a substrate for the monitoring of nucleotide pyrophosphatase/phosphodiesterase activities","year":2012,"lang":"en","type":"article","venue":"Journal of Chromatography B","topic":"Adenosine and Purinergic Signaling","field":"Biochemistry, Genetics and Molecular Biology","cited_by":20,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université Laval; Centre hospitalier universitaire de Québec","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; Capillary electrophoresis; Chromatography; Detection limit; Micellar electrokinetic chromatography; Substrate (aquarium); Electrophoresis; Capillary action","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006327119,0.0002825507,0.000446645,0.0001490103,0.0001905299,0.00003841718,0.0002370615,0.0001262392,0.000005419969],"category_scores_gemma":[0.00007505628,0.0002086155,0.00053942,0.0002758926,0.0001191554,0.00004225537,0.00005858331,0.0001800527,2.79595e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002342827,"about_ca_system_score_gemma":0.0001324843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001120551,"about_ca_topic_score_gemma":7.523784e-7,"domain_scores_codex":[0.9983744,0.0001202649,0.0005950904,0.0001789144,0.0002778962,0.0004534273],"domain_scores_gemma":[0.998263,0.0002139674,0.0008004421,0.0002632267,0.000302344,0.0001570139],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001134884,0.0001184024,0.009248202,0.00007091171,0.0009328139,0.00002492315,0.0003137158,0.0006581539,0.9862631,0.00005905519,0.0008273681,0.0003484634],"study_design_scores_gemma":[0.0008577466,0.0005758125,0.00274486,0.0001081381,0.0004003424,0.0002452547,0.001001996,0.00009029479,0.992,0.00007904735,0.001665386,0.0002311111],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.937757,0.05379347,0.00771923,0.00005103396,0.0004165243,0.0002098017,0.0000314058,0.000006061191,0.00001551052],"genre_scores_gemma":[0.9768971,0.00325695,0.01881682,0.0000698681,0.0008802654,0.000009137274,0.000007558694,0.00004900656,0.00001326246],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05053652,"threshold_uncertainty_score":0.8507095,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01442321532533573,"score_gpt":0.2825353648811822,"score_spread":0.2681121495558464,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}