{"id":"W2056013246","doi":"10.1002/jssc.201100754","title":"Optimization and validation of a fast ultrahigh‐pressure liquid chromatographic method for simultaneous determination of selected sulphonamides in water samples using a fully porous sub‐2 μm column at elevated temperature","year":2011,"lang":"en","type":"article","venue":"Journal of Separation Science","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chromatography; Chemistry; Porosity; Column (typography); High-performance liquid chromatography; Analytical Chemistry (journal)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001931883,0.001112443,0.0008671432,0.0005805713,0.0004091345,0.0006400623,0.0007415056,0.00110486,0.0003702166],"category_scores_gemma":[0.001179594,0.0005442167,0.000762864,0.0003781562,0.000741473,0.0005486779,0.0005127401,0.0006852689,0.0003532028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005920976,"about_ca_system_score_gemma":0.001447461,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001225132,"about_ca_topic_score_gemma":0.002951753,"domain_scores_codex":[0.9980851,0.0004508907,0.0001304625,0.0002976153,0.0009522717,0.00008360764],"domain_scores_gemma":[0.9993513,0.0001874868,0.0001259258,0.00005315243,0.0002395034,0.00004262218],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003840378,0.0000414759,0.0001671933,0.00005204983,0.00001349338,0.00002568145,0.00001444944,0.0001225072,0.9966819,0.00003207467,0.0000113718,0.002799365],"study_design_scores_gemma":[0.00004243023,0.0009796728,0.003912081,0.00001562894,0.0000554734,0.0003690199,0.0000263633,0.004138643,0.9891317,0.00005499694,0.001245876,0.00002815365],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.7572451,0.004991165,0.2351638,0.0001784882,0.0001347293,0.0005527667,0.0003803426,0.0004937325,0.0008598056],"genre_scores_gemma":[0.6322342,0.002957091,0.3605964,0.0001680639,0.00006288203,0.0006819967,0.0008280998,0.00007367601,0.002397637],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.001931883,"threshold_uncertainty_score":0.01021683,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03035994545578435,"score_gpt":0.3189690082796965,"score_spread":0.2886090628239122,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}