{"id":"W2056028641","doi":"10.1039/c3cc48823c","title":"Rhodium/phospholane–phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenes","year":2013,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Optech (Canada)","funders":"","keywords":"Hydroformylation; Regioselectivity; Enantioselective synthesis; Rhodium; Chemistry; Catalysis; Ligand (biochemistry); Organic chemistry; Vinyl acetate; Solvent; Combinatorial chemistry; Copolymer; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003201676,0.0006590808,0.0003490675,0.0002276605,0.0001666572,0.0003893577,0.000352506,0.0003593284,0.002251394],"category_scores_gemma":[0.0003332676,0.0002812559,0.0002603296,0.0001741699,0.0003474203,0.0003396892,0.0003957462,0.0005700331,0.001430904],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002307726,"about_ca_system_score_gemma":0.0002131073,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000685675,"about_ca_topic_score_gemma":0.001581206,"domain_scores_codex":[0.9997446,0.00003851345,0.0000218129,0.00004724629,0.00007346199,0.00007441339],"domain_scores_gemma":[0.9998723,0.00003281255,0.00002569513,0.00002223964,0.00001734903,0.00002947431],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001110766,0.00002469073,0.000121619,0.00007498697,0.00001034776,0.0001833569,0.00003567601,0.0001679895,0.995178,0.0002083355,0.0001245025,0.003759564],"study_design_scores_gemma":[0.000009420382,0.00005015255,0.0002518909,0.00000206561,0.00000543274,0.00013079,0.000006920863,0.000157505,0.9986076,0.00001563189,0.0007595958,0.000003014012],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824255,0.001152553,0.005671904,0.0002025404,0.00004098663,0.0000441411,0.0003135916,0.0002709937,0.009877723],"genre_scores_gemma":[0.9917163,0.0007707063,0.00229648,0.00003945206,0.0000118638,0.00001019216,0.0003636112,0.00006870465,0.0047227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002251394,"threshold_uncertainty_score":0.007531643,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01506987920722575,"score_gpt":0.22883710242578,"score_spread":0.2137672232185542,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}