{"id":"W2056041008","doi":"10.1021/om049034w","title":"Synthesis and Reactivity of New κ<sup>2</sup>-[<i>P</i>,<i>N</i>]Pt(II) Complexes of Diisopropylphosphino-Substituted 2-Dimethylaminoindene","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Indene; Reactivity (psychology); Yield (engineering); Isomerization; Ligand (biochemistry); Medicinal chemistry; Toluene; Intramolecular force; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004135139,0.0005557608,0.001380355,0.0002788379,0.0001915236,0.00004430621,0.0006816613,0.0002700528,0.0187282],"category_scores_gemma":[0.0005138695,0.0005331597,0.0003922556,0.0008570687,0.000454928,0.0003919448,0.0003960412,0.0002858482,0.00003280194],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009675424,"about_ca_system_score_gemma":0.0001805634,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003714079,"about_ca_topic_score_gemma":0.00006350313,"domain_scores_codex":[0.9969302,0.00004650534,0.0010805,0.0007511791,0.0006698329,0.0005217646],"domain_scores_gemma":[0.9971441,0.0004907181,0.0006653357,0.001212741,0.0001679432,0.0003191855],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007725428,0.0007493947,0.002082473,0.0002932961,0.0005721956,0.000003444961,0.0007806031,0.00009398833,0.8740194,0.001241085,0.00009213248,0.1199947],"study_design_scores_gemma":[0.0005827335,0.00004016247,0.003013871,0.00008254053,0.0005961628,0.00002375395,0.0002586881,0.0004288848,0.9634472,0.0003130119,0.03067341,0.000539573],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.989669,0.002123828,0.0001994814,0.0003975041,0.00002561423,0.0001395894,0.0001857266,0.0001078747,0.007151385],"genre_scores_gemma":[0.9918873,0.0005431885,0.003622275,0.00003004797,0.0002059567,0.00001484782,0.00004786562,0.00009204444,0.003556527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1194552,"threshold_uncertainty_score":0.999712,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01607090335647609,"score_gpt":0.2212267808312287,"score_spread":0.2051558774747526,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}